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- W4296295636 abstract "Abstract The best use of photogenerated electrons and holes is crucial to boosting photocatalytic activity. Herein, a bifunctional dual‐cocatalyst‐modified photocatalyst is constructed based on CdS/MoO 2 /MoS 2 hollow spheres for hydrogen evolution coupled with selective pyruvic acid (PA) production from lactic acid (LA) oxidation. MoS 2 and MoO 2 are simultaneously obtained from the conversion of CdMoO 4 in one step. In a photocatalytic process, the MoS 2 and MoO 2 function as the reduction and oxidation centers on which photogenerated electrons and holes accumulate and are used for hydrogen evolution reaction (HER) and PA synthesis, respectively. By monitoring the intermediates, a two‐step single‐electron route for PA production is proposed, initiated by the cleavage of the α‐C(sp 3 )−H bond in the LA. The conversion of LA and the selectivity of PA can reach ca . 29 % and 95 % after a five‐hour reaction, respectively." @default.
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- W4296295636 date "2022-10-05" @default.
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- W4296295636 title "A Bifunctional CdS/MoO<sub>2</sub>/MoS<sub>2</sub> Catalyst Enhances Photocatalytic H<sub>2</sub> Evolution and Pyruvic Acid Synthesis" @default.
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- W4296295636 doi "https://doi.org/10.1002/ange.202212045" @default.
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