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- W4296297571 abstract "(Bi)carbonate adsorption on Cu(100) in 0.1 M KHCO3 has been studied by in situ scanning tunneling microscopy. Coexistence of different ordered adlayer phases with ( 2${sqrt{2}}$ ×6 2${sqrt{2}}$ )R45° and (4×4) unit cells was observed in the double layer potential regime. The adlayer is rather dynamic and undergoes a reversible order-disorder phase transition at 0 V vs. the reversible hydrogen electrode. Density functional calculations indicate that the adlayer consists of coadsorbed carbonate and water molecules and is strongly stabilized by liquid water in the adjacent electrolyte." @default.
- W4296297571 created "2022-09-19" @default.
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- W4296297571 date "2022-10-13" @default.
- W4296297571 modified "2023-09-30" @default.
- W4296297571 title "Structure of the (Bi)carbonate Adlayer on Cu(100) Electrodes" @default.
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- W4296297571 doi "https://doi.org/10.1002/anie.202211360" @default.
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