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• W4296354590 endingPage "1318" @default.
• W4296354590 startingPage "1318" @default.
• W4296354590 abstract "It has been shown that a nonchiral anisotropic macromolecule embedded in a chiral dielectric solvent possesses an effective optical activity proportional to the optical activity of the solvent. As a result, there exists an effective chiral interaction between the macromolecules, which creates a torque acting on the primary axes of the two interacting molecules. A general expression for the effective chiral interaction potential has been derived in terms of the effective polarizability and the effective gyration tensor of the macromolecule in the chiral solvent. Explicit expressions for the components of the effective polarizability and the gyration have been obtained using the model of a hard rod filled with anisotropic dielectric and embedded into the isotropic chiral dielectric medium. The theory predicts the formation of the cholesteric helical structure in the nematic polymer liquid crystal phase induced by a chiral solvent." @default.
• W4296354590 created "2022-09-20" @default.
• W4296354590 creator A5053085042 @default.
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• W4296354590 date "2022-09-18" @default.
• W4296354590 modified "2023-09-25" @default.
• W4296354590 title "Effective Chiral Interactions between Nonchiral Rigid Macromolecules in a Chiral Solvent and the Induced Cholesteric Liquid Crystal Phase" @default.
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• W4296354590 doi "https://doi.org/10.3390/cryst12091318" @default.
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