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- W4296598197 endingPage "11748" @default.
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- W4296598197 abstract "Controllable ortho-C–H arylation of aryl phosphines would provide a foundation for the modular synthesis of electronically and sterically tunable biaryl phosphines. However, this central task is challenging owing to the unfavorable four-membered cyclometalation and high tendency to undergo further interannular arylation. Herein phenolic compounds have been found to be effective ligands to determine single, double, or triple C–H arylation at will, providing a streamlined and practical synthetic approach to access (diaryl)- and (dialkyl)-biarylphosphines. The phosphine ligand library has been proven to be effective in catalytic coupling reactions and even exhibits unique chemoselectivity in comparison with commercially available classic phosphine ligands." @default.
- W4296598197 created "2022-09-22" @default.
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- W4296598197 date "2022-09-13" @default.
- W4296598197 modified "2023-10-13" @default.
- W4296598197 title "Ligand-Determined Single, Double, and Triple C–H Arylation of Aryl Phosphines at Will" @default.
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- W4296598197 doi "https://doi.org/10.1021/acscatal.2c03994" @default.
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