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• W4296673029 abstract "Narciindole A, the first representative of Amaryllidaceae alkaloids with an indol-3-ylmethanone framework, was isolated from bulbs of Narcissus pseudonarcissus (L.) cv. Carlton, together with carltonine D and carltonine E, which share the same unusual structural motif as dimeric carltonine C (reported in 2020), exhibiting atropisomerism. Unambiguous structure elucidations have been achieved by NMR spectroscopy, HRMS, and comparison with literature data of related alkaloids. Furthermore, the chirality of known alkaloids with a galanthindole biaryl core was revised using optical rotation. Last, but not least, a biosynthetic pathway for dimeric carltonine-type alkaloids was proposed. Unfortunately, in terms of biological activity, the isolated alkaloids showed only moderate inhibition of human acetylcholinesterase and/or butyrylcholinesterase." @default.
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• W4296673029 date "2022-12-01" @default.
• W4296673029 modified "2023-10-16" @default.
• W4296673029 title "Structural analysis of unusual alkaloids isolated from Narcissus pseudonarcissus cv. Carlton" @default.
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• W4296673029 doi "https://doi.org/10.1016/j.phytochem.2022.113439" @default.
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