FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4296800178> ?p ?o ?g. }

• W4296800178 endingPage "7675" @default.
• W4296800178 startingPage "7664" @default.
• W4296800178 abstract "Membrane models assembled on electrodes are widely used tools to study potential-dependent molecular processes at or in membranes. However, the relationship between the electrode potential and the potential across the membrane is not known. Here we studied lipid bilayers immobilized on mixed self-assembled monolayers (SAM) on Au electrodes. The mixed SAM was composed of thiol derivatives of different chain lengths such that between the islands of the short one, mercaptobenzonitrile (MBN), and the tethered lipid bilayer an aqueous compartment was formed. The nitrile function of MBN, which served as a reporter group for the vibrational Stark effect (VSE), was probed by surface-enhanced infrared absorption spectroscopy to determine the local electric field as a function of the electrode potential for pure MBN, mixed SAM, and the bilayer system. In parallel, we calculated electric fields at the VSE probe by molecular dynamics (MD) simulations for different charge densities on the metal, thereby mimicking electrode potential changes. The agreement with the experiments was very good for the calculations of the pure MBN SAM and only slightly worse for the mixed SAM. The comparison with the experiments also guided the design of the bilayer system in the MD setups, which were selected to calculate the electrode potential dependence of the transmembrane potential, a quantity that is not directly accessible by the experiments. The results agree very well with estimates in previous studies and thus demonstrate that the present combined experimental-theoretical approach is a promising tool for describing potential-dependent processes at biomimetic interfaces." @default.
• W4296800178 created "2022-09-24" @default.
• W4296800178 creator A5013708805 @default.
• W4296800178 creator A5030742505 @default.
• W4296800178 creator A5037633517 @default.
• W4296800178 creator A5047157719 @default.
• W4296800178 creator A5061107587 @default.
• W4296800178 creator A5072335125 @default.
• W4296800178 date "2022-09-22" @default.
• W4296800178 modified "2023-10-16" @default.
• W4296800178 title "Potential Distribution across Model Membranes" @default.
• W4296800178 cites W1492340685 @default.
• W4296800178 cites W1968564655 @default.
• W4296800178 cites W1969302686 @default.
• W4296800178 cites W1970583462 @default.
• W4296800178 cites W1972800394 @default.
• W4296800178 cites W1976499671 @default.
• W4296800178 cites W1976757597 @default.
• W4296800178 cites W1977493423 @default.
• W4296800178 cites W1978974783 @default.
• W4296800178 cites W1982898268 @default.
• W4296800178 cites W2004873002 @default.
• W4296800178 cites W2006154982 @default.
• W4296800178 cites W2013807009 @default.
• W4296800178 cites W2016510178 @default.
• W4296800178 cites W2021125439 @default.
• W4296800178 cites W2021520922 @default.
• W4296800178 cites W2023894941 @default.
• W4296800178 cites W2029667189 @default.
• W4296800178 cites W2033233860 @default.
• W4296800178 cites W2038758364 @default.
• W4296800178 cites W2041155376 @default.
• W4296800178 cites W2045670143 @default.
• W4296800178 cites W2058308323 @default.
• W4296800178 cites W2064719117 @default.
• W4296800178 cites W2066580949 @default.
• W4296800178 cites W2067174909 @default.
• W4296800178 cites W2068522177 @default.
• W4296800178 cites W2088245200 @default.
• W4296800178 cites W2088847815 @default.
• W4296800178 cites W2094577804 @default.
• W4296800178 cites W2103636724 @default.
• W4296800178 cites W2108595869 @default.
• W4296800178 cites W2111138318 @default.
• W4296800178 cites W2122072234 @default.
• W4296800178 cites W2122765546 @default.
• W4296800178 cites W2132262459 @default.
• W4296800178 cites W2133091224 @default.
• W4296800178 cites W2135581873 @default.
• W4296800178 cites W2135828619 @default.
• W4296800178 cites W2140403358 @default.
• W4296800178 cites W2140950672 @default.
• W4296800178 cites W2144887721 @default.
• W4296800178 cites W2145732570 @default.
• W4296800178 cites W2149434199 @default.
• W4296800178 cites W2150981663 @default.
• W4296800178 cites W2206954826 @default.
• W4296800178 cites W2291789711 @default.
• W4296800178 cites W2336774231 @default.
• W4296800178 cites W2399172722 @default.
• W4296800178 cites W2599649240 @default.
• W4296800178 cites W2748258251 @default.
• W4296800178 cites W2754831792 @default.
• W4296800178 cites W2770216832 @default.
• W4296800178 cites W2784449992 @default.
• W4296800178 cites W2807136758 @default.
• W4296800178 cites W2887564232 @default.
• W4296800178 cites W2908916379 @default.
• W4296800178 cites W2917550741 @default.
• W4296800178 cites W2942248766 @default.
• W4296800178 cites W2998968401 @default.
• W4296800178 cites W3037134643 @default.
• W4296800178 cites W3134483450 @default.
• W4296800178 cites W4229024056 @default.
• W4296800178 doi "https://doi.org/10.1021/acs.jpcb.2c05372" @default.
• W4296800178 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36137267" @default.
• W4296800178 hasPublicationYear "2022" @default.
• W4296800178 type Work @default.
• W4296800178 citedByCount "3" @default.
• W4296800178 countsByYear W42968001782023 @default.
• W4296800178 crossrefType "journal-article" @default.
• W4296800178 hasAuthorship W4296800178A5013708805 @default.
• W4296800178 hasAuthorship W4296800178A5030742505 @default.
• W4296800178 hasAuthorship W4296800178A5037633517 @default.
• W4296800178 hasAuthorship W4296800178A5047157719 @default.
• W4296800178 hasAuthorship W4296800178A5061107587 @default.
• W4296800178 hasAuthorship W4296800178A5072335125 @default.
• W4296800178 hasConcept C113196181 @default.
• W4296800178 hasConcept C121332964 @default.
• W4296800178 hasConcept C147597530 @default.
• W4296800178 hasConcept C147789679 @default.
• W4296800178 hasConcept C159467904 @default.
• W4296800178 hasConcept C17525397 @default.
• W4296800178 hasConcept C178790620 @default.
• W4296800178 hasConcept C181911157 @default.
• W4296800178 hasConcept C185592680 @default.
• W4296800178 hasConcept C18787249 @default.
• W4296800178 hasConcept C192157962 @default.

• next