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- W4296953499 abstract "• Pt/TiO 2 catalysts with different Pt aggregation sizes were prepared. • Hydrogenation activity of Pt/TiO 2 showed a volcano-shaped trend with Pt sizes. • Pt activity ranks in the order of nanometer cluster > nanoparticle > single atom. • Relationships between Pt activity and structural/electronic property were discussed. Supported metal catalysts often consist of metal sites ranging from nanoparticles to subnanometer clusters and single atoms. It remains a necessity to differentiate these sites to guide design of optimal catalysts. Here we report a simple method to assess the distribution of metal active sites in catalyst samples. The method takes the advantage of the structure sensitivity of styrene hydrogenation over titania supported platinum (Pt) catalysts with Pt aggregates varied from single atom to ∼1.40 nm nanoparticles. The physicochemical properties were characterized by STEM, XPS, XANES, H 2 -TPR and CO-chemisorption measurements. The reactivity of Pt sites was quantified by styrene hydrogenation at ambient conditions. The nanometer-sized Pt clusters have significantly higher activity than Pt nanoparticles, sub-nanometer clusters or isolated single atoms. The relationship between activity and structural/electronic properties of Pt sites influenced by particle sizes was discussed. Similar relationship was found in the carbon supported Pt catalysts." @default.
- W4296953499 created "2022-09-25" @default.
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- W4296953499 date "2022-10-01" @default.
- W4296953499 modified "2023-10-16" @default.
- W4296953499 title "Differentiating supported platinum single atoms, clusters and nanoparticles by styrene hydrogenation" @default.
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- W4296953499 doi "https://doi.org/10.1016/j.mcat.2022.112709" @default.
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