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- W4296959098 abstract "Rh-catalyzed dynamic kinetic intramolecular [4+2] cycloaddition reaction of 1,3-disubstituted allene-1,3-dienes afforded cis-fused [4.3.0]bicyclic products with an excellent chemo-, diastereo-, and enantio-selectivity. Many synthetically useful functional groups are tolerated. The synthetic utility has been demonstrated. Based on the careful experimental studies, a mechanism involving the rapid racemization of the allene moiety in the starting materials has been proposed." @default.
- W4296959098 created "2022-09-25" @default.
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- W4296959098 date "2022-10-21" @default.
- W4296959098 modified "2023-10-16" @default.
- W4296959098 title "Rhodium‐Catalyzed Dynamic Kinetic [4+2] Cycloaddition of Allene‐1,3‐Dienes" @default.
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- W4296959098 doi "https://doi.org/10.1002/anie.202211635" @default.
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