FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4297016543> ?p ?o ?g. }

• W4297016543 abstract "The dehydrogenation of abundant alkane feedstocks to olefins is one of the mostly intensively investigated reactions in organic catalysis. A long-standing, pervasive challenge in this transformation is the direct dehydrogenation of unactivated 1,1-disubstituted ethane, an aliphatic motif commonly found in organic molecules. Here, we report the design of a diphosphine chloroiridium catalyst for undirected dehydrogenation of this aliphatic class to form valuable 1,1-disubstituted ethylene. Featuring high site selectivity and excellent functional group compatibility, this catalytic system is applicable to late-stage dehydrogenation of complex bioactive molecules. Moreover, the system enables unprecedented dehydrogenation of polypropene with controllable degree of desaturation, dehydrogenating more than 10 in 100 propene units. Further derivatizations of the resulting double bonds afford functionalized polypropenes." @default.
• W4297016543 created "2022-09-25" @default.
• W4297016543 creator A5012635301 @default.
• W4297016543 creator A5013249496 @default.
• W4297016543 creator A5026143643 @default.
• W4297016543 creator A5033486450 @default.
• W4297016543 creator A5068508373 @default.
• W4297016543 creator A5087174977 @default.
• W4297016543 date "2022-09-23" @default.
• W4297016543 modified "2023-10-14" @default.
• W4297016543 title "Selective dehydrogenation of small and large molecules by a chloroiridium catalyst" @default.
• W4297016543 cites W1965931193 @default.
• W4297016543 cites W1978008449 @default.
• W4297016543 cites W1979007101 @default.
• W4297016543 cites W1984912819 @default.
• W4297016543 cites W1986862252 @default.
• W4297016543 cites W1988712786 @default.
• W4297016543 cites W1993798851 @default.
• W4297016543 cites W1996900902 @default.
• W4297016543 cites W1996923858 @default.
• W4297016543 cites W2005268263 @default.
• W4297016543 cites W2005661768 @default.
• W4297016543 cites W2007307094 @default.
• W4297016543 cites W2011695546 @default.
• W4297016543 cites W2017449422 @default.
• W4297016543 cites W2018099022 @default.
• W4297016543 cites W2024091154 @default.
• W4297016543 cites W2035438145 @default.
• W4297016543 cites W2040471549 @default.
• W4297016543 cites W2043974496 @default.
• W4297016543 cites W2051904273 @default.
• W4297016543 cites W2052403708 @default.
• W4297016543 cites W2060176306 @default.
• W4297016543 cites W2068041429 @default.
• W4297016543 cites W2069708019 @default.
• W4297016543 cites W2082039974 @default.
• W4297016543 cites W2086466871 @default.
• W4297016543 cites W2087231440 @default.
• W4297016543 cites W2109679704 @default.
• W4297016543 cites W2111894677 @default.
• W4297016543 cites W2117487885 @default.
• W4297016543 cites W2137792706 @default.
• W4297016543 cites W2141725143 @default.
• W4297016543 cites W2256889165 @default.
• W4297016543 cites W2262047238 @default.
• W4297016543 cites W2262768996 @default.
• W4297016543 cites W2293468919 @default.
• W4297016543 cites W2313438656 @default.
• W4297016543 cites W2318542822 @default.
• W4297016543 cites W2324208632 @default.
• W4297016543 cites W2444352686 @default.
• W4297016543 cites W2566254482 @default.
• W4297016543 cites W2608897458 @default.
• W4297016543 cites W2760777285 @default.
• W4297016543 cites W2762098462 @default.
• W4297016543 cites W2777651827 @default.
• W4297016543 cites W2947030310 @default.
• W4297016543 cites W3003428996 @default.
• W4297016543 cites W3024719448 @default.
• W4297016543 cites W3093279035 @default.
• W4297016543 cites W3100755484 @default.
• W4297016543 cites W3110953338 @default.
• W4297016543 cites W3199943476 @default.
• W4297016543 cites W3202404212 @default.
• W4297016543 cites W3203248815 @default.
• W4297016543 cites W3211073624 @default.
• W4297016543 cites W3213760854 @default.
• W4297016543 doi "https://doi.org/10.1126/sciadv.abo6586" @default.
• W4297016543 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36149964" @default.
• W4297016543 hasPublicationYear "2022" @default.
• W4297016543 type Work @default.
• W4297016543 citedByCount "3" @default.
• W4297016543 countsByYear W42970165432023 @default.
• W4297016543 crossrefType "journal-article" @default.
• W4297016543 hasAuthorship W4297016543A5012635301 @default.
• W4297016543 hasAuthorship W4297016543A5013249496 @default.
• W4297016543 hasAuthorship W4297016543A5026143643 @default.
• W4297016543 hasAuthorship W4297016543A5033486450 @default.
• W4297016543 hasAuthorship W4297016543A5068508373 @default.
• W4297016543 hasAuthorship W4297016543A5087174977 @default.
• W4297016543 hasBestOaLocation W42970165431 @default.
• W4297016543 hasConcept C118792377 @default.
• W4297016543 hasConcept C119889771 @default.
• W4297016543 hasConcept C127413603 @default.
• W4297016543 hasConcept C161790260 @default.
• W4297016543 hasConcept C178790620 @default.
• W4297016543 hasConcept C185592680 @default.
• W4297016543 hasConcept C21951064 @default.
• W4297016543 hasConcept C2777954637 @default.
• W4297016543 hasConcept C2778597550 @default.
• W4297016543 hasConcept C2778648169 @default.
• W4297016543 hasConcept C2781327020 @default.
• W4297016543 hasConcept C2984497647 @default.
• W4297016543 hasConcept C32909587 @default.
• W4297016543 hasConcept C42360764 @default.
• W4297016543 hasConcept C75473681 @default.
• W4297016543 hasConceptScore W4297016543C118792377 @default.
• W4297016543 hasConceptScore W4297016543C119889771 @default.
• W4297016543 hasConceptScore W4297016543C127413603 @default.
• W4297016543 hasConceptScore W4297016543C161790260 @default.

• next