Matches in SemOpenAlex for { <https://semopenalex.org/work/W4297092885> ?p ?o ?g. }
- W4297092885 endingPage "398" @default.
- W4297092885 startingPage "391" @default.
- W4297092885 abstract "Chemoselective hydrogenation of biomass platform molecules into value-added chemicals and fuels is essential for the exploitation of biomass, and SBA-15 based metal catalysts with hydrogenation centers and acid sites seem promising in this regard. Valeric acid (VA) is the most important platform molecule for valeric biofuels and value-added chemicals production. The main issue with using such bifunctional catalysts for biomass conversion is maintaining the catalyst's stability in the liquid phase under harsh conditions. In-addition, direct one-pot selective hydrogenation of levulinic acid (LA) into VA synthesis is challenging due to its complex reaction conditions involved. Herein, we design a bifunctional mesoporous catalysts (SBA-15 mesoporous material doped with various metals Nb, Ti, and Zr) investigated for this reaction under the vapour phase. Different instrumental approaches were used to examine the structure, phase composition, morphology, and surface elemental analyses of catalysts as-prepared. Among those catalysts, Zr-doped mesoporous SBA-15 catalyst showed the 91% conversion of LA and the 68% selectivity toward VA and promising stability in a 52 h time on-stream run. Metal dispersion inside the SBA-15 and their surface acidity (sufficient number of acid sites and surface-active metal oxide species) and higher surface area are beneficial for the selectivity of VA. This work offers a highly-efficient bifunctional catalyst for selective hydrogenation of biomass feedstocks." @default.
- W4297092885 created "2022-09-27" @default.
- W4297092885 creator A5007820612 @default.
- W4297092885 creator A5008006200 @default.
- W4297092885 creator A5041006685 @default.
- W4297092885 creator A5066263194 @default.
- W4297092885 creator A5081924615 @default.
- W4297092885 creator A5082925013 @default.
- W4297092885 creator A5089205224 @default.
- W4297092885 date "2022-01-01" @default.
- W4297092885 modified "2023-10-01" @default.
- W4297092885 title "Direct cascade hydrogenation of biorenewable levulinic acid to valeric acid biofuel additives over metal (M = Nb, Ti, and Zr) supported SBA-15 catalysts" @default.
- W4297092885 cites W1636962008 @default.
- W4297092885 cites W1853208221 @default.
- W4297092885 cites W1974732512 @default.
- W4297092885 cites W1977902200 @default.
- W4297092885 cites W1988360609 @default.
- W4297092885 cites W1988745485 @default.
- W4297092885 cites W1991205252 @default.
- W4297092885 cites W1992030014 @default.
- W4297092885 cites W2004636495 @default.
- W4297092885 cites W2006053803 @default.
- W4297092885 cites W2010770071 @default.
- W4297092885 cites W2013143289 @default.
- W4297092885 cites W2025917423 @default.
- W4297092885 cites W2040550723 @default.
- W4297092885 cites W2044851992 @default.
- W4297092885 cites W2046468736 @default.
- W4297092885 cites W2055054878 @default.
- W4297092885 cites W2056061112 @default.
- W4297092885 cites W2064758807 @default.
- W4297092885 cites W2080936170 @default.
- W4297092885 cites W2094691659 @default.
- W4297092885 cites W2102318977 @default.
- W4297092885 cites W2151863166 @default.
- W4297092885 cites W2238856570 @default.
- W4297092885 cites W2302359126 @default.
- W4297092885 cites W2688648259 @default.
- W4297092885 cites W2767193848 @default.
- W4297092885 cites W2880257815 @default.
- W4297092885 cites W2883285461 @default.
- W4297092885 cites W2953863349 @default.
- W4297092885 cites W2996230600 @default.
- W4297092885 cites W2996495479 @default.
- W4297092885 cites W3006919080 @default.
- W4297092885 cites W3011015563 @default.
- W4297092885 cites W3046046903 @default.
- W4297092885 cites W3094071578 @default.
- W4297092885 cites W3122859194 @default.
- W4297092885 cites W3130913431 @default.
- W4297092885 cites W3165259679 @default.
- W4297092885 cites W3170970747 @default.
- W4297092885 cites W3217236420 @default.
- W4297092885 cites W4214561933 @default.
- W4297092885 cites W4214881411 @default.
- W4297092885 cites W4285034808 @default.
- W4297092885 cites W4297988264 @default.
- W4297092885 doi "https://doi.org/10.1016/j.mset.2022.09.006" @default.
- W4297092885 hasPublicationYear "2022" @default.
- W4297092885 type Work @default.
- W4297092885 citedByCount "2" @default.
- W4297092885 countsByYear W42970928852022 @default.
- W4297092885 countsByYear W42970928852023 @default.
- W4297092885 crossrefType "journal-article" @default.
- W4297092885 hasAuthorship W4297092885A5007820612 @default.
- W4297092885 hasAuthorship W4297092885A5008006200 @default.
- W4297092885 hasAuthorship W4297092885A5041006685 @default.
- W4297092885 hasAuthorship W4297092885A5066263194 @default.
- W4297092885 hasAuthorship W4297092885A5081924615 @default.
- W4297092885 hasAuthorship W4297092885A5082925013 @default.
- W4297092885 hasAuthorship W4297092885A5089205224 @default.
- W4297092885 hasBestOaLocation W42970928851 @default.
- W4297092885 hasConcept C111368507 @default.
- W4297092885 hasConcept C115540264 @default.
- W4297092885 hasConcept C118792377 @default.
- W4297092885 hasConcept C127313418 @default.
- W4297092885 hasConcept C127413603 @default.
- W4297092885 hasConcept C161790260 @default.
- W4297092885 hasConcept C178790620 @default.
- W4297092885 hasConcept C179104552 @default.
- W4297092885 hasConcept C185592680 @default.
- W4297092885 hasConcept C192562407 @default.
- W4297092885 hasConcept C2776258393 @default.
- W4297092885 hasConcept C2776673659 @default.
- W4297092885 hasConcept C2779412933 @default.
- W4297092885 hasConcept C2780443040 @default.
- W4297092885 hasConcept C2780604391 @default.
- W4297092885 hasConcept C42360764 @default.
- W4297092885 hasConcept C82776694 @default.
- W4297092885 hasConceptScore W4297092885C111368507 @default.
- W4297092885 hasConceptScore W4297092885C115540264 @default.
- W4297092885 hasConceptScore W4297092885C118792377 @default.
- W4297092885 hasConceptScore W4297092885C127313418 @default.
- W4297092885 hasConceptScore W4297092885C127413603 @default.
- W4297092885 hasConceptScore W4297092885C161790260 @default.
- W4297092885 hasConceptScore W4297092885C178790620 @default.
- W4297092885 hasConceptScore W4297092885C179104552 @default.
- W4297092885 hasConceptScore W4297092885C185592680 @default.