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• W4297150761 abstract "Green methanol is a viable alternative for the storage of hydrogen and may be produced from captured anthropogenic sources of carbon dioxide. The latter was hydrogenated over Cu-ZnO catalysts supported on an aluminum fumarate metal-organic framework (AlFum MOF). The catalysts, prepared via slurry phase impregnation, were assessed for thermocatalytic hydrogenation of CO2 to methanol. PXRD, FTIR, and SBET exhibited a decrease in crystallinity of the AlFum MOF support after impregnation with Cu-Zn active sites. SEM, SEM-EDS, and TEM revealed that the morphology of the support is preserved after metal loading, where H2-TPR confirmed the presence of active sites for hydrogen uptake. The catalysts exhibited good activity, with a doubling in Cu and Zn loading over the AlFum MOF, resulting in a 4-fold increase in CO2 conversions from 10.8% to 45.6% and an increase in methanol productivity from 34.4 to 56.5 gMeOH/Kgcat/h. The catalysts exhibited comparatively high CO selectivity and high yields of H2O, thereby favoring the reverse water-gas shift reaction. The selectivity of the catalysts towards methanol was found to be 12.9% and 6.9%. The performance of the catalyst supported on AlFum MOF further highlights the potential use of MOFs as supports in the heterogeneous thermocatalytic conversion of CO2 to value-added products." @default.
• W4297150761 created "2022-09-27" @default.
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• W4297150761 date "2022-09-24" @default.
• W4297150761 modified "2023-09-30" @default.
• W4297150761 title "Towards High CO2 Conversions Using Cu/Zn Catalysts Supported on Aluminum Fumarate Metal-Organic Framework for Methanol Synthesis" @default.
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• W4297150761 doi "https://doi.org/10.3390/catal12101104" @default.
• W4297150761 hasPublicationYear "2022" @default.
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