Matches in SemOpenAlex for { <https://semopenalex.org/work/W4297181004> ?p ?o ?g. }
- W4297181004 endingPage "266" @default.
- W4297181004 startingPage "257" @default.
- W4297181004 abstract "The adsorption, thermal chemistry, and catalytic hydrogenation of acrolein on copper model surfaces was characterized by a combination of surface-science techniques, namely, reflection–absorption infrared spectroscopy (RAIRS) and temperature program desorption (TPD), quantum mechanics (DFT) calculations, and catalytic kinetic measurements using a so-called “high-pressure cell”. Adsorption of acrolein on the Cu surface was found to involve both the carbonyl oxygen atom and the CC bond. Thermal activation leads to early dissociation and dehydrogenation to produce acetylene and carbon monoxide below 160 K, and later to the production of ketene (220 K) and propene (260 K). Under vacuum hydrogenation with H2 is not possible, but upon predosing of the surface with atomic H all the possible hydrogenation products, namely, propanal, 1-propanol, and allyl alcohol, were detected in TPD experiments, at 162, 190, and 210 K, respectively. Finally, catalytic hydrogenation under atmospheric pressures is slow and only produces propanal, at turnover frequencies below 0.2 s−1." @default.
- W4297181004 created "2022-09-27" @default.
- W4297181004 creator A5011552496 @default.
- W4297181004 creator A5067483347 @default.
- W4297181004 creator A5073605632 @default.
- W4297181004 creator A5074539493 @default.
- W4297181004 creator A5086850505 @default.
- W4297181004 date "2022-10-01" @default.
- W4297181004 modified "2023-10-05" @default.
- W4297181004 title "Adsorption, thermal conversion, and catalytic hydrogenation of acrolein on Cu surfaces" @default.
- W4297181004 cites W1164028207 @default.
- W4297181004 cites W1966174540 @default.
- W4297181004 cites W1968309474 @default.
- W4297181004 cites W1970127494 @default.
- W4297181004 cites W1979523591 @default.
- W4297181004 cites W1981368803 @default.
- W4297181004 cites W1981639638 @default.
- W4297181004 cites W1981823857 @default.
- W4297181004 cites W1983554181 @default.
- W4297181004 cites W1983669046 @default.
- W4297181004 cites W1989229321 @default.
- W4297181004 cites W1995448204 @default.
- W4297181004 cites W1997304953 @default.
- W4297181004 cites W2003662667 @default.
- W4297181004 cites W2008127349 @default.
- W4297181004 cites W2011764801 @default.
- W4297181004 cites W2020954056 @default.
- W4297181004 cites W2029904786 @default.
- W4297181004 cites W2029969667 @default.
- W4297181004 cites W2031430816 @default.
- W4297181004 cites W2035870651 @default.
- W4297181004 cites W2037551624 @default.
- W4297181004 cites W2050867865 @default.
- W4297181004 cites W2051624205 @default.
- W4297181004 cites W2052733245 @default.
- W4297181004 cites W2060036338 @default.
- W4297181004 cites W2064156452 @default.
- W4297181004 cites W2066518701 @default.
- W4297181004 cites W2066683734 @default.
- W4297181004 cites W2083222334 @default.
- W4297181004 cites W2086330469 @default.
- W4297181004 cites W2092157292 @default.
- W4297181004 cites W2113820064 @default.
- W4297181004 cites W2122427541 @default.
- W4297181004 cites W2154254816 @default.
- W4297181004 cites W2176997977 @default.
- W4297181004 cites W2267714992 @default.
- W4297181004 cites W2287633368 @default.
- W4297181004 cites W2312825882 @default.
- W4297181004 cites W2331179437 @default.
- W4297181004 cites W2345588669 @default.
- W4297181004 cites W2427322902 @default.
- W4297181004 cites W2464029424 @default.
- W4297181004 cites W2575249235 @default.
- W4297181004 cites W2579601412 @default.
- W4297181004 cites W2583327956 @default.
- W4297181004 cites W2730432668 @default.
- W4297181004 cites W2736780366 @default.
- W4297181004 cites W2784356185 @default.
- W4297181004 cites W2789790823 @default.
- W4297181004 cites W2792179921 @default.
- W4297181004 cites W2800244740 @default.
- W4297181004 cites W2802306478 @default.
- W4297181004 cites W2891355668 @default.
- W4297181004 cites W2892068630 @default.
- W4297181004 cites W2901366977 @default.
- W4297181004 cites W2905123457 @default.
- W4297181004 cites W2920190408 @default.
- W4297181004 cites W2940983774 @default.
- W4297181004 cites W2943768465 @default.
- W4297181004 cites W2952023060 @default.
- W4297181004 cites W2953994773 @default.
- W4297181004 cites W2972988649 @default.
- W4297181004 cites W2990812066 @default.
- W4297181004 cites W2994746008 @default.
- W4297181004 cites W3001728099 @default.
- W4297181004 cites W3003370668 @default.
- W4297181004 cites W3008199853 @default.
- W4297181004 cites W3037620337 @default.
- W4297181004 cites W3042233572 @default.
- W4297181004 cites W3090244366 @default.
- W4297181004 cites W3094383754 @default.
- W4297181004 cites W3134113354 @default.
- W4297181004 cites W3185760845 @default.
- W4297181004 cites W3193091868 @default.
- W4297181004 cites W3207917001 @default.
- W4297181004 cites W4221049396 @default.
- W4297181004 cites W4230542669 @default.
- W4297181004 cites W657336152 @default.
- W4297181004 doi "https://doi.org/10.1016/j.jcat.2022.09.013" @default.
- W4297181004 hasPublicationYear "2022" @default.
- W4297181004 type Work @default.
- W4297181004 citedByCount "4" @default.
- W4297181004 countsByYear W42971810042023 @default.
- W4297181004 crossrefType "journal-article" @default.
- W4297181004 hasAuthorship W4297181004A5011552496 @default.
- W4297181004 hasAuthorship W4297181004A5067483347 @default.
- W4297181004 hasAuthorship W4297181004A5073605632 @default.