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• W4297239519 abstract "An unprecedented copper-catalyzed cascade reaction of 1,6-enynes with sulfoxonium ylides is reported, providing a series of structurally intriguing 2,3-disubstituted indolines bearing a conjugated dienone functionality at the 3-position in moderate to excellent yields with good chemo-, regio-, and diastereoselectivities under mild reaction conditions. Importantly, sulfoxonium-ylide-derived copper-carbene herein exhibits quite different reactivity from that of diazo copper-carbene. A rational mechanism, an initial ammonium ylide rather than allene formation, is proposed." @default.
• W4297239519 created "2022-09-28" @default.
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• W4297239519 date "2022-09-26" @default.
• W4297239519 modified "2023-10-18" @default.
• W4297239519 title "Unexpected Copper-Catalyzed Cascade Reaction of 1,6-Enynes with Sulfoxonium Ylides" @default.
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• W4297239519 doi "https://doi.org/10.1021/acs.orglett.2c02620" @default.
• W4297239519 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36154184" @default.
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