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• W4297243569 abstract "A systematic study to access stable stannaimines is reported, by combining different heteroleptic stannylenes with a range of organic azides. The reactions of terphenyl-/hypersilyl-substituted stannylenes yield the putative tin nitrogen double bond, but is directly followed by 1,2-silyl migration to give SnII systems featuring bulky silylamido ligands. By contrast, the transition from a two σ donor ligand set to a mixed σ-donor/π-donor scaffold allows access to three new stannaimines which can be handled at room temperature. The reactivity profile of these Sn=N bonded species is crucially dependent on the substituent at the nitrogen atom. As such, the Sn=NMes (Mes=2,4,6-Me3C6H2) system is capable of activating a broad range of substrates under ambient conditions via 1,2-addition reactions, [2+2] and [4+2] cycloaddition reactions. Most interestingly, very rare examples of main group multiple bond metathesis reactions are also found to be viable." @default.
• W4297243569 created "2022-09-28" @default.
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• W4297243569 date "2022-10-25" @default.
• W4297243569 modified "2023-10-03" @default.
• W4297243569 title "Taming Heavier Group 14 Imine Analogues: Accessing Tin Nitrogen [Sn=N] Double Bonds and their Cycloaddition/Metathesis Chemistry" @default.
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• W4297243569 doi "https://doi.org/10.1002/ange.202211616" @default.
• W4297243569 hasPublicationYear "2022" @default.
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