FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4297839773> ?p ?o ?g. }

• W4297839773 endingPage "134159" @default.
• W4297839773 startingPage "134159" @default.
• W4297839773 abstract "The crystal structure of 2-hydroxy-4-methylbenzenesulfonic acid salts С6Н3(СН3)(ОН)SO3−М+ where М+ = NH4+, K+, Rb+ and Cs+ has been determined by X-ray diffraction method at 150 K. All salts are characterized by the same space symmetry group P 21/c, Z = 4 (Final R is 0.0382, 0.0309, 0.0272 and 0.0288 respectively). The С6Н3(СН3)(ОН)SO3−anion is in a common position as well as ammonium and alkali metal cations. In the crystal structure of each salt a rather weak hydrogen bond С–SO3−…НО–С is formed between the ОН group and the oxygen atom of the sulfogroup belonging to the neighboring C6H3(CH3)(OH)SO3− anion. Polycrystalline samples С6Н3(СН3)(ОН)SO3−М+ where М+ = NH4+, K+, Rb+ and Cs+ and С6Н3(СН3)(ОD)SO3−М+ where М+ = ND4+, K+, Rb+ and Cs+ have been studied by ATR FTIR and Raman spectroscopy in the frequency range 50–4000 cm−1. It is proposed an assignment of the –SO3− group vibrational frequencies as well as of the OH and OD groups (for the internal and external vibrations). The anion site symmetry is C1, but the –SO3− local symmetry estimated by spectroscopic methods is nearly ∼C3V. The concentration dependence of the ν(ОН), ν(ОD), ν(NH) and ν(ND) contours on the content of hydrogen isotopes was analyzed by FTIR and Raman spectroscopy. Dependence of the ν(ОН) and ν(ОD) widths on a degree of isotopic H–D dilution is weak, which can serve as a sign of some disorder in the hydrogen atoms positions." @default.
• W4297839773 created "2022-10-01" @default.
• W4297839773 creator A5013821637 @default.
• W4297839773 creator A5015761916 @default.
• W4297839773 creator A5023221086 @default.
• W4297839773 creator A5038249193 @default.
• W4297839773 creator A5067333800 @default.
• W4297839773 date "2023-01-01" @default.
• W4297839773 modified "2023-09-26" @default.
• W4297839773 title "Сrystal structure and vibrational spectra of NH4+, K+, Rb+ and Cs+ salts of the 2-hydroxy-4-methylbenzenesulfonic acid" @default.
• W4297839773 cites W1968151352 @default.
• W4297839773 cites W1972178934 @default.
• W4297839773 cites W1981799320 @default.
• W4297839773 cites W1993467926 @default.
• W4297839773 cites W2001123876 @default.
• W4297839773 cites W2009643348 @default.
• W4297839773 cites W2013992032 @default.
• W4297839773 cites W2025862083 @default.
• W4297839773 cites W2030160492 @default.
• W4297839773 cites W2035591552 @default.
• W4297839773 cites W2041579714 @default.
• W4297839773 cites W2045978065 @default.
• W4297839773 cites W2055753848 @default.
• W4297839773 cites W2057370123 @default.
• W4297839773 cites W2070883382 @default.
• W4297839773 cites W2150767188 @default.
• W4297839773 cites W2156485901 @default.
• W4297839773 cites W2472155866 @default.
• W4297839773 cites W2792392103 @default.
• W4297839773 cites W2792968846 @default.
• W4297839773 cites W2796149115 @default.
• W4297839773 cites W2898309209 @default.
• W4297839773 doi "https://doi.org/10.1016/j.molstruc.2022.134159" @default.
• W4297839773 hasPublicationYear "2023" @default.
• W4297839773 type Work @default.
• W4297839773 citedByCount "0" @default.
• W4297839773 crossrefType "journal-article" @default.
• W4297839773 hasAuthorship W4297839773A5013821637 @default.
• W4297839773 hasAuthorship W4297839773A5015761916 @default.
• W4297839773 hasAuthorship W4297839773A5023221086 @default.
• W4297839773 hasAuthorship W4297839773A5038249193 @default.
• W4297839773 hasAuthorship W4297839773A5067333800 @default.
• W4297839773 hasConcept C112887158 @default.
• W4297839773 hasConcept C113196181 @default.
• W4297839773 hasConcept C115624301 @default.
• W4297839773 hasConcept C120665830 @default.
• W4297839773 hasConcept C121332964 @default.
• W4297839773 hasConcept C145148216 @default.
• W4297839773 hasConcept C153642686 @default.
• W4297839773 hasConcept C160892712 @default.
• W4297839773 hasConcept C178790620 @default.
• W4297839773 hasConcept C179104552 @default.
• W4297839773 hasConcept C184779094 @default.
• W4297839773 hasConcept C185592680 @default.
• W4297839773 hasConcept C198091228 @default.
• W4297839773 hasConcept C32909587 @default.
• W4297839773 hasConcept C40003534 @default.
• W4297839773 hasConcept C43617362 @default.
• W4297839773 hasConcept C512968161 @default.
• W4297839773 hasConcept C58364064 @default.
• W4297839773 hasConcept C62520636 @default.
• W4297839773 hasConcept C8010536 @default.
• W4297839773 hasConceptScore W4297839773C112887158 @default.
• W4297839773 hasConceptScore W4297839773C113196181 @default.
• W4297839773 hasConceptScore W4297839773C115624301 @default.
• W4297839773 hasConceptScore W4297839773C120665830 @default.
• W4297839773 hasConceptScore W4297839773C121332964 @default.
• W4297839773 hasConceptScore W4297839773C145148216 @default.
• W4297839773 hasConceptScore W4297839773C153642686 @default.
• W4297839773 hasConceptScore W4297839773C160892712 @default.
• W4297839773 hasConceptScore W4297839773C178790620 @default.
• W4297839773 hasConceptScore W4297839773C179104552 @default.
• W4297839773 hasConceptScore W4297839773C184779094 @default.
• W4297839773 hasConceptScore W4297839773C185592680 @default.
• W4297839773 hasConceptScore W4297839773C198091228 @default.
• W4297839773 hasConceptScore W4297839773C32909587 @default.
• W4297839773 hasConceptScore W4297839773C40003534 @default.
• W4297839773 hasConceptScore W4297839773C43617362 @default.
• W4297839773 hasConceptScore W4297839773C512968161 @default.
• W4297839773 hasConceptScore W4297839773C58364064 @default.
• W4297839773 hasConceptScore W4297839773C62520636 @default.
• W4297839773 hasConceptScore W4297839773C8010536 @default.
• W4297839773 hasFunder F4320321912 @default.
• W4297839773 hasLocation W42978397731 @default.
• W4297839773 hasOpenAccess W4297839773 @default.
• W4297839773 hasPrimaryLocation W42978397731 @default.
• W4297839773 hasRelatedWork W2014324318 @default.
• W4297839773 hasRelatedWork W2039374736 @default.
• W4297839773 hasRelatedWork W2039710977 @default.
• W4297839773 hasRelatedWork W2063401985 @default.
• W4297839773 hasRelatedWork W2072417293 @default.
• W4297839773 hasRelatedWork W2767205953 @default.
• W4297839773 hasRelatedWork W2788975530 @default.
• W4297839773 hasRelatedWork W2942835415 @default.
• W4297839773 hasRelatedWork W4365512430 @default.
• W4297839773 hasRelatedWork W646380683 @default.
• W4297839773 hasVolume "1272" @default.
• W4297839773 isParatext "false" @default.

• next