Matches in SemOpenAlex for { <https://semopenalex.org/work/W4297849062> ?p ?o ?g. }
Showing items 1 to 83 of
83
with 100 items per page.
- W4297849062 abstract "Solid-state synthesis represents an alternative to solution-phase chemistry that can provide routes to materials typically unobtainable by conventional methods. However, multiple competing reaction pathways under high-pressure conditions makes the targeted synthesis of chemically homogeneous systems a challenge. Nanothreads, one-dimensional diamondoid polymers formed through the compression of aromatic hydrocarbons present a unique opportunity to carry out high pressure reactions in a controlled and predictable manner. We hypothesize that through careful consideration of molecular stacking and intermolecular forces (e.g., H-bonding), it is possible to form chemically homogeneous nanothreads that retain precisely located chemical functionality. Herein, we report the scalable solid-state polymerization of 2,5-furandicarboxylic acid through sequential [4 + 2] Diels Alder cycloaddition reactions. The resulting nanothread product is decorated with a high density of pendant carboxylate groups, presenting new opportunities for post-synthetic processing and functional applications. Transition metal coordination is demonstrated for the functionalized threads, representing proof-of-concept for the utilization of nanothreads as independent synthons and the possibility for novel, extended multidimensional networks." @default.
- W4297849062 created "2022-10-01" @default.
- W4297849062 creator A5010769205 @default.
- W4297849062 creator A5028922875 @default.
- W4297849062 creator A5042484439 @default.
- W4297849062 creator A5053099185 @default.
- W4297849062 creator A5061542791 @default.
- W4297849062 creator A5067483347 @default.
- W4297849062 creator A5079969652 @default.
- W4297849062 creator A5081902176 @default.
- W4297849062 date "2022-09-09" @default.
- W4297849062 modified "2023-09-30" @default.
- W4297849062 title "Synthesis and Post-Processing of Chemically Homogeneous Nanothreads from 2,5-Furandicarboxylic Acid" @default.
- W4297849062 doi "https://doi.org/10.26434/chemrxiv-2022-45nt5" @default.
- W4297849062 hasPublicationYear "2022" @default.
- W4297849062 type Work @default.
- W4297849062 citedByCount "0" @default.
- W4297849062 crossrefType "posted-content" @default.
- W4297849062 hasAuthorship W4297849062A5010769205 @default.
- W4297849062 hasAuthorship W4297849062A5028922875 @default.
- W4297849062 hasAuthorship W4297849062A5042484439 @default.
- W4297849062 hasAuthorship W4297849062A5053099185 @default.
- W4297849062 hasAuthorship W4297849062A5061542791 @default.
- W4297849062 hasAuthorship W4297849062A5067483347 @default.
- W4297849062 hasAuthorship W4297849062A5079969652 @default.
- W4297849062 hasAuthorship W4297849062A5081902176 @default.
- W4297849062 hasBestOaLocation W42978490621 @default.
- W4297849062 hasConcept C121332964 @default.
- W4297849062 hasConcept C161790260 @default.
- W4297849062 hasConcept C166950319 @default.
- W4297849062 hasConcept C171250308 @default.
- W4297849062 hasConcept C178790620 @default.
- W4297849062 hasConcept C185592680 @default.
- W4297849062 hasConcept C192562407 @default.
- W4297849062 hasConcept C21951064 @default.
- W4297849062 hasConcept C2778074193 @default.
- W4297849062 hasConcept C2779664164 @default.
- W4297849062 hasConcept C32909587 @default.
- W4297849062 hasConcept C33347731 @default.
- W4297849062 hasConcept C40869318 @default.
- W4297849062 hasConcept C44228677 @default.
- W4297849062 hasConcept C521977710 @default.
- W4297849062 hasConcept C66882249 @default.
- W4297849062 hasConcept C90104038 @default.
- W4297849062 hasConcept C93275456 @default.
- W4297849062 hasConcept C97355855 @default.
- W4297849062 hasConceptScore W4297849062C121332964 @default.
- W4297849062 hasConceptScore W4297849062C161790260 @default.
- W4297849062 hasConceptScore W4297849062C166950319 @default.
- W4297849062 hasConceptScore W4297849062C171250308 @default.
- W4297849062 hasConceptScore W4297849062C178790620 @default.
- W4297849062 hasConceptScore W4297849062C185592680 @default.
- W4297849062 hasConceptScore W4297849062C192562407 @default.
- W4297849062 hasConceptScore W4297849062C21951064 @default.
- W4297849062 hasConceptScore W4297849062C2778074193 @default.
- W4297849062 hasConceptScore W4297849062C2779664164 @default.
- W4297849062 hasConceptScore W4297849062C32909587 @default.
- W4297849062 hasConceptScore W4297849062C33347731 @default.
- W4297849062 hasConceptScore W4297849062C40869318 @default.
- W4297849062 hasConceptScore W4297849062C44228677 @default.
- W4297849062 hasConceptScore W4297849062C521977710 @default.
- W4297849062 hasConceptScore W4297849062C66882249 @default.
- W4297849062 hasConceptScore W4297849062C90104038 @default.
- W4297849062 hasConceptScore W4297849062C93275456 @default.
- W4297849062 hasConceptScore W4297849062C97355855 @default.
- W4297849062 hasFunder F4320306253 @default.
- W4297849062 hasFunder F4320338281 @default.
- W4297849062 hasLocation W42978490621 @default.
- W4297849062 hasOpenAccess W4297849062 @default.
- W4297849062 hasPrimaryLocation W42978490621 @default.
- W4297849062 hasRelatedWork W2004249730 @default.
- W4297849062 hasRelatedWork W2043003877 @default.
- W4297849062 hasRelatedWork W2043541768 @default.
- W4297849062 hasRelatedWork W2076455212 @default.
- W4297849062 hasRelatedWork W2085774937 @default.
- W4297849062 hasRelatedWork W2137683587 @default.
- W4297849062 hasRelatedWork W2316141378 @default.
- W4297849062 hasRelatedWork W2323257994 @default.
- W4297849062 hasRelatedWork W2328529321 @default.
- W4297849062 hasRelatedWork W2519673346 @default.
- W4297849062 isParatext "false" @default.
- W4297849062 isRetracted "false" @default.
- W4297849062 workType "article" @default.