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- W4297884030 abstract "New heterometallic hydride complexes that involve the addition of {Mg−H} and {Zn−H} bonds to group 10 transition metals (Pd, Pt) are reported. The side-on coordination of a single {Mg−H} to Pd forms a well-defined σ-complex. In contrast, addition of three {Mg−H} or {Zn−H} bonds to Pd or Pt results in the formation of planar complexes with subtly different geometries. We compare their structures through experiment (X-ray diffraction, neutron diffraction, multinuclear NMR), computational methods (DFT, QTAIM, NCIPlot), and theoretical analysis (MO diagram, Walsh diagram). These species can be described as snapshots along a continuum of bonding between ideal trigonal planar and hexagonal planar geometries." @default.
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- W4297884030 date "2022-10-05" @default.
- W4297884030 modified "2023-10-16" @default.
- W4297884030 title "The Continuum Between Hexagonal Planar and Trigonal Planar Geometries**" @default.
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- W4297884030 doi "https://doi.org/10.1002/ange.202211948" @default.
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