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- W4298008866 endingPage "123633" @default.
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- W4298008866 abstract "Volatile organic compounds (VOCs) cause great harm to the ecological environment and human health. Metal-organic frameworks (MOFs) are one of the high-performance adsorbents for the removal of VOCs. A typical MOFs material MIL-101(Cr) was prepared by hydrothermal synthesis, and the properties of the material were optimized by doping copper ions. All prepared adsorbents were characterized by XRD, FTIR, SEM, TG and N2 adsorption-desorption. The results showed that [email protected](Cr) with different Cu2+ doping content was successfully prepared without changing the framework structure of MIL-101(Cr). However, the surface area and pore size of [email protected](Cr) were reduced, the crystallinity and thermal stability were influenced by varying degrees. Among the samples, [email protected](Cr) expressed the best adsorption ability on toluene due to the introduction of unsaturated metal sites by doped copper ions, which could improve the adsorption performance of MIL-101(Cr), and its saturation adsorption capacity could reach 469 mg/g. Although Cu2+ doping reduced the specific surface area of the material, the increased active sites could greatly improve the adsorption performance of the material, meanwhile the desorption efficiency of [email protected](Cr) could also reach 86% after 5 times cycles." @default.
- W4298008866 created "2022-10-01" @default.
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- W4298008866 date "2022-12-01" @default.
- W4298008866 modified "2023-10-14" @default.
- W4298008866 title "Stable effect on MIL-101(Cr) with Cu2+ for the toluene adsorption" @default.
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- W4298008866 doi "https://doi.org/10.1016/j.jssc.2022.123633" @default.
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