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- W4300002247 abstract "Abstract The nucleophilic addition of organometallic reagents to aldehydes, ketones, imines, and electron‐deficient alkenes is one of the most classic and useful methods to construct organic compounds. Normally, prehalogenation of substrates and the use of stoichiometric amounts of metals to prepare air and moisture‐sensitive organometallic reagents are inevitable. Along with the flourish of CH activation in the last two decades, transition metal‐catalyzed direct addition of inert CH bonds to polar multiple bonds (e.g. CO and CN) has aroused great interest of chemists for its superior atom and step economy. Though great success has been accomplished in this area, controlling the stereoselectivity of such reactions is still a big challenge. In this article, we would like to provide an overview of the advances in transition metal‐catalyzed asymmetric addition of CH bond to carbonyls, imines, and electron‐deficient alkenes, which may assist the development of this field. It is divided into three sections, (i) asymmetric addition of CH bond to carbonyls, (ii) asymmetric addition of CH bond to imines, and (iii) asymmetric addition of CH bond to electron‐deficient alkenes. The discussion of each reaction mainly consists of strategies used to control stereochemistry, selected examples of products with reaction outcomes, and reaction mechanism." @default.
- W4300002247 created "2022-10-03" @default.
- W4300002247 creator A5042241049 @default.
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- W4300002247 date "2022-10-02" @default.
- W4300002247 modified "2023-10-16" @default.
- W4300002247 title "Asymmetric Addition of Inert CH Bond to Carbonyls, Imines, and Electron‐Deficient Alkenes" @default.
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- W4300002247 doi "https://doi.org/10.1002/9783527834242.chf0025" @default.
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