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- W4300002502 abstract "The synthesis of non-racemic 5-membered cyclic carbonates from abundant alcohols is reported. Conversion of the alcohol into an azanyl carbonate is followed by a chiral-at-ruthenium catalyzed cyclization to provide chiral cyclic carbonates in yields of up to 95% and with up to 99% ee. This new synthetic method is proposed to proceed through a nitrene-mediated intramolecular C(sp 3 )−H oxygenation which includes a very unusual 1,7-hydrogen atom transfer within a ruthenium nitrenoid intermediate. The method is applicable to the synthesis of non-racemic chiral mono-, di- and trisubstituted cyclic alkylene carbonates." @default.
- W4300002502 created "2022-10-03" @default.
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- W4300002502 date "2022-10-26" @default.
- W4300002502 modified "2023-10-17" @default.
- W4300002502 title "Nitrene‐Mediated C−H Oxygenation: Catalytic Enantioselective Formation of Five‐Membered Cyclic Organic Carbonates" @default.
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- W4300002502 doi "https://doi.org/10.1002/ange.202211971" @default.
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