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- W4300576319 abstract "Several molybdenum compounds—oxides, sulfide, metal, carbide, and nitride—were prepared, and their catalytic properties in the methanation of CO at 350 °C were investigated and compared with those of nickel and iron. The initial specific activities, i.e., rates per unit surface area of catalyst, decreased in the following sequence: Ni > Mo carbide > Mo metal > Mo nitride > MoO2 > MoS2 > MoO3. The rate of aging, loss in activity for methanation, decreased in the following way: Fe > Mo carbide > Mo metal > Ni > MoS2 ∼- Mo nitride > MoO2. The zero-valent molybdenum compounds produced much larger amounts of C2 and C2 hydrocarbons than MoO2 and MoS2, and about the same amount as iron. Nickel produced the smallest amount of higher hydrocarbons. The molybdenum compounds except MoS2 and MoO3 had higher activities for the water-gas-shift reaction than nickel and iron. Molybdenum compounds were as active in 1H2 + 1CO gas as in 3H2 + 1CO feed; nickel and iron were substantially less active in the CO-rich gas." @default.
- W4300576319 created "2022-10-03" @default.
- W4300576319 date "1988-01-01" @default.
- W4300576319 modified "2023-09-26" @default.
- W4300576319 title "The water—gas shift reaction" @default.
- W4300576319 doi "https://doi.org/10.1016/s0166-9834(00)83041-9" @default.
- W4300576319 hasPublicationYear "1988" @default.
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