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• W4300689281 startingPage "7476" @default.
• W4300689281 abstract "Nonactivated alcohols along with arene compounds are used in electrochemical dehydroxylative arylation for constructing C(sp3)-C(sp2) bonds. The PIII reagent undergoes single-electron anodic oxidation to form its radical cation, which reacts with the alcohol to produce an alkoxytriphenylphosphine radical. Through spontaneous β-scission of the phosphoranyl radical, the C-O bond is cleaved to form an alkyl radical species, which couples with the radical anion generated by cathodic reduction of the electron-poor arene to afford the dehydroxylative arylated product." @default.
• W4300689281 created "2022-10-04" @default.
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• W4300689281 date "2022-10-03" @default.
• W4300689281 modified "2023-10-10" @default.
• W4300689281 title "Dehydroxylative Arylation of Alcohols via Paired Electrolysis" @default.
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• W4300689281 doi "https://doi.org/10.1021/acs.orglett.2c03136" @default.
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