Matches in SemOpenAlex for { <https://semopenalex.org/work/W4300690879> ?p ?o ?g. }
- W4300690879 endingPage "1910" @default.
- W4300690879 startingPage "1901" @default.
- W4300690879 abstract "The CO2 cycloaddition to epoxides is an efficient method for CO2 capture and storage, important not only for reducing greenhouse gas emission but also for producing cyclic carbonates, which are valuable industrial materials. In this study, we report a novel high-nuclearity titanium oxide cluster (TOC) inlayed with main-group element Pb2+, H2Ti16Pb9O24(SA)18(DMF)10(OH2)2 (denoted as 1; SA = salicylate; DMF = N,N-dimethylformamide), which has the property of visible-light absorption and has shown high catalytic activities for cycloadditions of CO2 under visible-light irradiation. The cluster was synthesized in a high yield in a facial solvothermal process. Its structure and electronic structure were characterized by single-crystal X-ray diffraction, density functional theory calculations, and complementary techniques. The cycloaddition reactions were performed under solvent-free conditions. While the catalytic activity due to the Lewis acidity was moderate, visible-light irradiation further folded the reaction rates. The turnover number reached 3400 with a turnover frequency of 120 h-1. Mechanism studies indicated a synergistic effect of the Lewis acidity and photogenerated charge carriers. The performance of 1 in reversible I2 uptake was also investigated. This study demonstrates the high potential of heterometal-decorated TOCs in the cost-effective and efficient CO2 cycloaddition reaction under mild conditions." @default.
- W4300690879 created "2022-10-04" @default.
- W4300690879 creator A5011516577 @default.
- W4300690879 creator A5017153875 @default.
- W4300690879 creator A5021779672 @default.
- W4300690879 creator A5031380067 @default.
- W4300690879 creator A5055728529 @default.
- W4300690879 creator A5061195656 @default.
- W4300690879 creator A5071062995 @default.
- W4300690879 creator A5075149791 @default.
- W4300690879 creator A5085596479 @default.
- W4300690879 date "2022-10-03" @default.
- W4300690879 modified "2023-10-14" @default.
- W4300690879 title "Lead-Decorated Titanium Oxide Compound with a High Performance in Catalytic CO<sub>2</sub> Insertion to Epoxides" @default.
- W4300690879 cites W1982371517 @default.
- W4300690879 cites W2038954174 @default.
- W4300690879 cites W2054634986 @default.
- W4300690879 cites W2059205366 @default.
- W4300690879 cites W2068899570 @default.
- W4300690879 cites W2091360328 @default.
- W4300690879 cites W2134005234 @default.
- W4300690879 cites W2161739806 @default.
- W4300690879 cites W2290797056 @default.
- W4300690879 cites W2299239881 @default.
- W4300690879 cites W2513342958 @default.
- W4300690879 cites W2700356249 @default.
- W4300690879 cites W2739042662 @default.
- W4300690879 cites W2770965322 @default.
- W4300690879 cites W2771397493 @default.
- W4300690879 cites W2803207959 @default.
- W4300690879 cites W2808651797 @default.
- W4300690879 cites W2884326411 @default.
- W4300690879 cites W2903434330 @default.
- W4300690879 cites W2905615800 @default.
- W4300690879 cites W2909822057 @default.
- W4300690879 cites W2911205981 @default.
- W4300690879 cites W2924710882 @default.
- W4300690879 cites W2966340006 @default.
- W4300690879 cites W2984973284 @default.
- W4300690879 cites W2988011221 @default.
- W4300690879 cites W2990933792 @default.
- W4300690879 cites W2993395882 @default.
- W4300690879 cites W2999050709 @default.
- W4300690879 cites W3013756521 @default.
- W4300690879 cites W3034940828 @default.
- W4300690879 cites W3037663615 @default.
- W4300690879 cites W3044706441 @default.
- W4300690879 cites W3080651299 @default.
- W4300690879 cites W3083912950 @default.
- W4300690879 cites W3103218042 @default.
- W4300690879 cites W3107364182 @default.
- W4300690879 cites W3117604063 @default.
- W4300690879 cites W3126650880 @default.
- W4300690879 cites W3133132039 @default.
- W4300690879 cites W3169562087 @default.
- W4300690879 cites W3171391346 @default.
- W4300690879 cites W3183781074 @default.
- W4300690879 cites W3184485456 @default.
- W4300690879 cites W3188229239 @default.
- W4300690879 cites W3197469733 @default.
- W4300690879 cites W3198287108 @default.
- W4300690879 cites W3201610856 @default.
- W4300690879 cites W3208763910 @default.
- W4300690879 cites W3212120117 @default.
- W4300690879 cites W3215367626 @default.
- W4300690879 cites W3216029271 @default.
- W4300690879 cites W3216922410 @default.
- W4300690879 cites W4200045042 @default.
- W4300690879 cites W4200537481 @default.
- W4300690879 cites W4206695685 @default.
- W4300690879 cites W4221062338 @default.
- W4300690879 cites W4283459261 @default.
- W4300690879 doi "https://doi.org/10.1021/acs.inorgchem.2c01315" @default.
- W4300690879 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36184952" @default.
- W4300690879 hasPublicationYear "2022" @default.
- W4300690879 type Work @default.
- W4300690879 citedByCount "4" @default.
- W4300690879 countsByYear W43006908792023 @default.
- W4300690879 crossrefType "journal-article" @default.
- W4300690879 hasAuthorship W4300690879A5011516577 @default.
- W4300690879 hasAuthorship W4300690879A5017153875 @default.
- W4300690879 hasAuthorship W4300690879A5021779672 @default.
- W4300690879 hasAuthorship W4300690879A5031380067 @default.
- W4300690879 hasAuthorship W4300690879A5055728529 @default.
- W4300690879 hasAuthorship W4300690879A5061195656 @default.
- W4300690879 hasAuthorship W4300690879A5071062995 @default.
- W4300690879 hasAuthorship W4300690879A5075149791 @default.
- W4300690879 hasAuthorship W4300690879A5085596479 @default.
- W4300690879 hasConcept C104663316 @default.
- W4300690879 hasConcept C115624301 @default.
- W4300690879 hasConcept C121332964 @default.
- W4300690879 hasConcept C15920480 @default.
- W4300690879 hasConcept C161790260 @default.
- W4300690879 hasConcept C178790620 @default.
- W4300690879 hasConcept C185592680 @default.
- W4300690879 hasConcept C2777505466 @default.
- W4300690879 hasConcept C2777801237 @default.
- W4300690879 hasConcept C2779664164 @default.