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- W4300717137 endingPage "2203852" @default.
- W4300717137 startingPage "2203852" @default.
- W4300717137 abstract "Sustainable production of hydrogen from seawater electrolysis has attracted much attention in recent years. Considering that Cl- might corrode metal substrate by crossing through the covered catalyst, the conventional Ni(II)Fe(III)-layered double hydroxide (NiFe-LDH) loaded on metal substrate, as a favorable oxygen evolution catalyst, cannot be directly used for seawater electrolysis. Herein, an anti-corrosion strategy of PO43- intercalation in NiFe-LDH is proposed, in which the highly negatively charged PO43- in the interlayers can prevent the Ni substrate from Cl- corrosion by electrostatic repulsion. In order to verify the anti-corrosion effect, the two electrodes of the pristine NiFe-LDH and the PO43- intercalated NiFe-LDH are evaluated in a solution with high Cl- concentration. PO43- can effectively hinder the migration of Cl- between the interlayers of NiFe-LDH, thus the corrosion life of the PO43- intercalated NiFe-LDH is more than 100 times longer than that of the pristine NiFe-LDH. The improvement of stability is attributed to the inhibition effect of Cl- passing through the interlayers of NiFe-LDH, leading to the protection of Ni substrate. This work provides a design strategy for the catalysts loaded on the metal substrate, which has excellent Cl- -corrosion resistance and can be widely used in hydrogen generation from seawater electrolysis." @default.
- W4300717137 created "2022-10-04" @default.
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- W4300717137 date "2022-10-03" @default.
- W4300717137 modified "2023-10-03" @default.
- W4300717137 title "High Corrosion Resistance of NiFe‐Layered Double Hydroxide Catalyst for Stable Seawater Electrolysis Promoted by Phosphate Intercalation" @default.
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- W4300717137 doi "https://doi.org/10.1002/smll.202203852" @default.
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