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- W4300860933 abstract "Silica-based aerogels bearing a novel aminophosphonate-containing substituent were prepared. Pd2+ and Cu2+ ions were introduced into aerogel matrix to form chelated complexes with aminophosphonate moiety. Both complexes securely retain Me2+ after supercritical drying (SCD) in CO2. In silica matrix, Pd complex is reduced to metallic Pd after treatment by gaseous H2 at 120 °C. In lyogel matrix, Pd complex can also be reduced to metallic Pd upon SCD in isopropanol. Pd-containing aerogel showed excellent catalytic activity in the reaction of C=C and C=Cbonds hydrogenation." @default.
- W4300860933 created "2022-10-04" @default.
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- W4300860933 date "2022-10-03" @default.
- W4300860933 modified "2023-09-26" @default.
- W4300860933 title "Novel aminophosphonate ligand for the preparation of catalytically active silica aerogels with finely dispersed palladium" @default.
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- W4300860933 doi "https://doi.org/10.1007/s10934-022-01357-4" @default.
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