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- W4300862694 endingPage "120183" @default.
- W4300862694 startingPage "120183" @default.
- W4300862694 abstract "It is a challenge to achieve the fully water-soluble chitosan. In this work, water-soluble chitosan-based probes were obtained by the following steps: boron-dipyrrolemethene (BODIPY)-OH was synthesized, and then BODIPY-OH was halogenated to BODIPY-Br. Afterwards, BODIPY-Br reacted with carbon disulfide and mercaptopropionic acid to obtain BODIPY-disulfide. BODIPY-disulfide was introduced to chitosan via amidation reaction to obtain fluorescent chitosan-thioester (CS-CTA); it is employed as the macro-initiator. Methacrylamide (MAm) was grafted onto chitosan fluorescent thioester through reversible addition-fragmentation chain transfer (RAFT) polymerization method. Thus, a water-soluble macromolecular probe (CS-g-PMAm) with chitosan as the main chain and PMAm as long-branched chains was obtained. It greatly improved the solubility in pure water. The thermal stability was reduced slightly, and the stickiness was greatly reduced and the samples displayed the characteristics of liquid. CS-g-PMAm could detect Fe3+ in pure water. By the same method, CS-g-PMAA (CS-g-Polymethylacrylic acid) was synthesized and investigated as well." @default.
- W4300862694 created "2022-10-04" @default.
- W4300862694 creator A5015825032 @default.
- W4300862694 creator A5047041068 @default.
- W4300862694 creator A5051831435 @default.
- W4300862694 date "2023-01-01" @default.
- W4300862694 modified "2023-10-16" @default.
- W4300862694 title "Water-soluble chitosan-g-PMAm (PMAA)-Bodipy probes prepared by RAFT methods for the detection of Fe3+ ion" @default.
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- W4300862694 doi "https://doi.org/10.1016/j.carbpol.2022.120183" @default.
- W4300862694 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36876798" @default.
- W4300862694 hasPublicationYear "2023" @default.
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