Matches in SemOpenAlex for { <https://semopenalex.org/work/W4301372699> ?p ?o ?g. }
- W4301372699 endingPage "46385" @default.
- W4301372699 startingPage "46374" @default.
- W4301372699 abstract "Metal-organic frameworks (MOFs) are considered potential electrocatalysts for efficient water splitting. However, the structure-activity relationship of most MOFs is not systematically analyzed for electrocatalysis for anodes and cathodes. In this paper, we provide a strategy to modulate the electronic microstructure of iron-based bimetallic MOFs (MFe-BDC (M: Mg, Zn, Cd)) grown on the nickel foam (NF) as bifunctional electrocatalysts for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). The optimal bimetallic CdFe-BDC via modulating appropriate metal cations of IIA and IIB possesses excellent OER and HER performance with the lowest overpotentials of 290 mV at 100 mA cm-2 and 148 mV at 10 mA cm-2, respectively. The overall water splitting performance of the as-prepared CdFe-BDC requires 1.68 V to achieve a current density of 10 mA cm-2 in the real seawater media, and it exhibits the competitive H2 and O2 production rates of 6.4 and 3.1 μL s-1, respectively, in ambient alkaline conditions, suggesting its potential practical applications. Density functional theory (DFT) calculations demonstrate the relationship between microstructure and electrocatalytic performance of bimetallic MFe-BDC. This work emphasizes the significance of tailoring the electronic microstructure of bimetallic MOFs for efficient overall water splitting in alkaline and seawater environment." @default.
- W4301372699 created "2022-10-05" @default.
- W4301372699 creator A5012324763 @default.
- W4301372699 creator A5019098369 @default.
- W4301372699 creator A5023028712 @default.
- W4301372699 creator A5035504703 @default.
- W4301372699 creator A5050215551 @default.
- W4301372699 creator A5052787170 @default.
- W4301372699 creator A5057193098 @default.
- W4301372699 creator A5067376138 @default.
- W4301372699 creator A5067512479 @default.
- W4301372699 creator A5088038198 @default.
- W4301372699 date "2022-10-04" @default.
- W4301372699 modified "2023-10-14" @default.
- W4301372699 title "Structural and Electronic Modulation of Iron-Based Bimetallic Metal–Organic Framework Bifunctional Electrocatalysts for Efficient Overall Water Splitting in Alkaline and Seawater Environment" @default.
- W4301372699 cites W2030622653 @default.
- W4301372699 cites W2053303098 @default.
- W4301372699 cites W2254778592 @default.
- W4301372699 cites W2276596429 @default.
- W4301372699 cites W2608006752 @default.
- W4301372699 cites W2762452954 @default.
- W4301372699 cites W2798187244 @default.
- W4301372699 cites W2805236843 @default.
- W4301372699 cites W2805322974 @default.
- W4301372699 cites W2807128433 @default.
- W4301372699 cites W2885150422 @default.
- W4301372699 cites W2885462854 @default.
- W4301372699 cites W2899206442 @default.
- W4301372699 cites W2907670431 @default.
- W4301372699 cites W2927052818 @default.
- W4301372699 cites W2973536416 @default.
- W4301372699 cites W2988071901 @default.
- W4301372699 cites W3016407157 @default.
- W4301372699 cites W3017337048 @default.
- W4301372699 cites W3026638249 @default.
- W4301372699 cites W3031615809 @default.
- W4301372699 cites W3049026356 @default.
- W4301372699 cites W3080683807 @default.
- W4301372699 cites W3087936024 @default.
- W4301372699 cites W3089604743 @default.
- W4301372699 cites W3093062968 @default.
- W4301372699 cites W3094465724 @default.
- W4301372699 cites W3095420917 @default.
- W4301372699 cites W3097805640 @default.
- W4301372699 cites W3116424349 @default.
- W4301372699 cites W3121728877 @default.
- W4301372699 cites W3129198355 @default.
- W4301372699 cites W3130540796 @default.
- W4301372699 cites W3134219571 @default.
- W4301372699 cites W3134618236 @default.
- W4301372699 cites W3135051793 @default.
- W4301372699 cites W3135082598 @default.
- W4301372699 cites W3136436906 @default.
- W4301372699 cites W3138381558 @default.
- W4301372699 cites W3162996684 @default.
- W4301372699 cites W3168227397 @default.
- W4301372699 cites W3169491658 @default.
- W4301372699 cites W3180962402 @default.
- W4301372699 cites W3183960520 @default.
- W4301372699 cites W3198911869 @default.
- W4301372699 cites W3202717577 @default.
- W4301372699 cites W3209820053 @default.
- W4301372699 cites W3212872539 @default.
- W4301372699 cites W3215747318 @default.
- W4301372699 cites W3216179139 @default.
- W4301372699 cites W3217033473 @default.
- W4301372699 cites W4200474114 @default.
- W4301372699 cites W4214563951 @default.
- W4301372699 cites W4220864085 @default.
- W4301372699 cites W4248407739 @default.
- W4301372699 doi "https://doi.org/10.1021/acsami.2c05181" @default.
- W4301372699 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36195560" @default.
- W4301372699 hasPublicationYear "2022" @default.
- W4301372699 type Work @default.
- W4301372699 citedByCount "19" @default.
- W4301372699 countsByYear W43013726992023 @default.
- W4301372699 crossrefType "journal-article" @default.
- W4301372699 hasAuthorship W4301372699A5012324763 @default.
- W4301372699 hasAuthorship W4301372699A5019098369 @default.
- W4301372699 hasAuthorship W4301372699A5023028712 @default.
- W4301372699 hasAuthorship W4301372699A5035504703 @default.
- W4301372699 hasAuthorship W4301372699A5050215551 @default.
- W4301372699 hasAuthorship W4301372699A5052787170 @default.
- W4301372699 hasAuthorship W4301372699A5057193098 @default.
- W4301372699 hasAuthorship W4301372699A5067376138 @default.
- W4301372699 hasAuthorship W4301372699A5067512479 @default.
- W4301372699 hasAuthorship W4301372699A5088038198 @default.
- W4301372699 hasConcept C127413603 @default.
- W4301372699 hasConcept C135473242 @default.
- W4301372699 hasConcept C147789679 @default.
- W4301372699 hasConcept C150394285 @default.
- W4301372699 hasConcept C161790260 @default.
- W4301372699 hasConcept C171250308 @default.
- W4301372699 hasConcept C17525397 @default.
- W4301372699 hasConcept C178790620 @default.
- W4301372699 hasConcept C179104552 @default.
- W4301372699 hasConcept C179366358 @default.
- W4301372699 hasConcept C185592680 @default.