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- W4301600730 abstract "The experimental discovery of four-layer orthorhombic (4O) martensite has added new research motivation to the Ni–Mn–Sn magnetic shape memory alloy. Herein, the martensitic transformation, magnetic properties, and electronic structures of Ni2Mn1+xSn1−x alloys are investigated using the first-principles calculations. The results show that the increasing Mn content destabilizes the stability of austenite (A) compared to the non-modulated (NM) martensite. This composition adjustment promotes the occurrence of martensitic transformation in the range of 0.375 ≤ x ≤ 0.75, and the corresponding phase transition sequence is A → 4O → NM during cooling. An intense hybridization bond exists between excess Mn and its surrounding atoms. The increasing antiferromagnetic interaction between excess Mn and normal Mn weakens each atomic moment and, thus, the total magnetic moment. Furthermore, the physical essence of the phase stability and magnetic properties variation with composition was explained based on the electronic density of states." @default.
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- W4301600730 date "2022-10-05" @default.
- W4301600730 modified "2023-10-08" @default.
- W4301600730 title "Composition-dependent phase transformation path involving 4O martensite in Ni–Mn–Sn magnetic shape memory alloys" @default.
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- W4301600730 doi "https://doi.org/10.1063/5.0107783" @default.
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