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- W4301622014 abstract "<p> In examining the utilization of transition metals in synthetic organic chemistry, iridium is not a metal which comes to the fore. In fact, while its family member, rhodium, sees extensive use for organic synthesis, iridium is pretty much ignored. However, there are quite a number of unusual bond-making and bond-breaking reactions that can occur at an iridium center that suggest that iridium be given a closer look. </p> <p> In this article, the organometallic chemistry of iridium will be reviewed with special attention paid to unusual transformations of organic groups that are attached to the metal. These include, C-H cleavage, C-C cleavage, as well as quite a number of other bond cleavage reactions such as 8-H, N-H, and O H. The chemistry of iridium with various heterocycles containing 0, N and S will also be discussed, especially the chemistry that has relevance to hydrodesulfurization chemistry. </p> <p> Beyond bond-breaking reactions, iridium is quite adept at facilitating quite a number of unusual bond-making reactions. The ability of iridium complexes for H-C, 8-C, C-C, and N-C bond-making chemistry will be covered. </p>" @default.
- W4301622014 created "2022-10-05" @default.
- W4301622014 creator A5006755559 @default.
- W4301622014 date "1997-09-01" @default.
- W4301622014 modified "2023-10-03" @default.
- W4301622014 title "Organic Chemistry at an Iridium Center: Unusual Bond-Making and Bond-Breaking Reactions" @default.
- W4301622014 doi "https://doi.org/10.2174/1385272801666220124192259" @default.
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