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- W4302012206 abstract "A Pd-catalyzed and photoinduced benzylic cascade benzylic C-H carbonylation/annulation reaction is realized under mild conditions (35 °C, 2 bar CO). The use of a catalytic amount of base is crucial for the reaction to achieve high yields. The reaction consists of a Pd-catalyzed generation of amidyl radical from O-benzyl hydroxylamide substrates and 1,5-HAT to give a benzylic radical, followed by carbonylation and annulation. Various homophthalimides, which could be readily converted to a number of bioactive compounds, could be obtained with up to 96% yield." @default.
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- W4302012206 date "2022-10-05" @default.
- W4302012206 modified "2023-10-12" @default.
- W4302012206 title "Palladium-Catalyzed and Photoinduced Benzylic C–H Carbonylation/Annulation under Mild Conditions" @default.
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- W4302012206 doi "https://doi.org/10.1021/acs.orglett.2c02877" @default.
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