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• W4302282143 abstract "Regardless of the many common properties shared by ionic liquids (ILs) and deep eutectic solvents (DES), these are two completely different classes of solvents. Unlike ILs, DES are not composed solely of ions, which adds an extra complexity to the systems. Indeed, DES possess a distinct nanostructure organization which is mainly due to the strong hydrogen network present in these solvents. For this reason ILs and DES cannot be treated as similar mixtures, having their own particularities and different promising applications. Nevertheless, both solvents are highly tunable owing to the infinite number of possible combinations of their components and so it is important to tailor their specific properties according to a specific task, by choosing the right components at the right molar ratios. The growing number of applications involving an IL/surface or DES/surface interface is increasing rapidly, but the upscaling of such technologies needs a profound knowledge of chemical compositions, structure and orientational arrangements at these interfaces, also known as the electrical double layer (EDL). In this work, we provide a summary of the progress made in the interfacial area involving ILs and DES, paying special attention to the EDL arrangements and dynamics. It is clear that classical EDL theories do not apply to neither of these solvents, being the one proposed by Kornyshev the most accepted for ILs. Yet, a multilayer organization of the mixtures components at the solvent|electrode interface is recognized by experimental and computational simulation communities for both electrolytes. Each system has its own characteristic differential capacitance curves, which vary greatly due to the different nature of adsorption/desorption species and their reorientation." @default.
• W4302282143 created "2022-10-06" @default.
• W4302282143 creator A5003958967 @default.
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• W4302282143 date "2023-01-01" @default.
• W4302282143 modified "2023-09-27" @default.
• W4302282143 title "Electrical double layer in ionic liquids and deep eutectic solvents" @default.
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• W4302282143 doi "https://doi.org/10.1016/b978-0-323-85669-0.00028-3" @default.
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