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- W4302773536 endingPage "110173" @default.
- W4302773536 startingPage "110173" @default.
- W4302773536 abstract "Endowing epoxy resins with enhanced flame retardancy, toughness and strength as well as glass transition temperature (Tg) simultaneously is a big challenge in academia and industry fields. Herein, a hyperbranched multifunctional additive (PEIP-Fe) was designed, which was prepared through a Mannich condensation reaction of polyethyleneimine and phosphorous acid and followed by combining with ferric. When 3 wt% of PEIP-Fe was incorporated into epoxy resin, the impact strength, tensile strength, flexural strength and Tg were all enhanced due to the multiple toughening mechanisms, good compatibility and the increased cross-linking density. Simultaneously, fire safety such as flame retardancy, smoke suppression and toxicity were all improved. The flame-retardant mechanism was verified in both condensed-phase and gas-phase by catalytic charring and free radical scavenging, forming compact and continuous char layer and releasing phosphorus-containing species respectively. This work provides new thinking for the design of multifunctional and high efficiency additives for epoxy resin." @default.
- W4302773536 created "2022-10-07" @default.
- W4302773536 creator A5041737780 @default.
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- W4302773536 date "2022-12-01" @default.
- W4302773536 modified "2023-10-01" @default.
- W4302773536 title "Simultaneously improving the fire safety and mechanical properties of epoxy resin with iron phosphonated grafted polyethylenimine" @default.
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- W4302773536 doi "https://doi.org/10.1016/j.polymdegradstab.2022.110173" @default.
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