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- W4303022014 abstract "Abstract Confined space provides a reaction platform with altered reaction rate and selectivity compared with a homogeneous solution. In this work, porous phenolic pillar[5]arene crystals were used as a reaction space to promote and perturb equilibrium between lactones and their corresponding polyesters. Immersion of porous pillar[5]arene crystals in liquid lactones induced ring‐opening polymerization of δ‐valerolactone and ϵ‐caprolactone at room temperature because the phenolic hydroxy groups have catalytic activity via hydrogen bonds and the pillar[5]arene cavities prefer linear guests. After the reaction, pillar[5]arene and polyesters formed pseudo‐polyrotaxanes." @default.
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- W4303022014 date "2022-11-10" @default.
- W4303022014 modified "2023-10-16" @default.
- W4303022014 title "Room‐Temperature Ring‐Opening Polymerization of δ‐Valerolactone and ϵ‐Caprolactone Caused by Uptake into Porous Pillar[5]arene Crystals" @default.
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- W4303022014 doi "https://doi.org/10.1002/anie.202212874" @default.
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