FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4303453721> ?p ?o ?g. }

• W4303453721 endingPage "102256" @default.
• W4303453721 startingPage "102256" @default.
• W4303453721 abstract "The construction of three-dimensional hierarchical porous and hydrophobic-aerophilic interfaces facilitates mass transport and CO2 enrichment by kinetically accelerating the CO2 electrochemical reduction reaction (CO2RR). Inspired by the process of baking bread, in which pores that connect the interior of the bread to its exterior are created, we propose a template-free metal carbonate-porous metal oxide (MC-PMO) strategy to synthesize porous metal oxides with tunable pore size. Using this strategy, a series of porous metal oxides with different morphologies and different metals was successfully developed. Furthermore, the effect of catalyst mass transport on the CO2RR was explored. The porous catalysts with suitable pore size promoted mass transfer, which significantly enhanced the activation and transformation of CO2. In addition, based on a hydrophobic group-modified metal oxide surface (HG-MO) strategy, a hydrophobic-aerophilic interface microenvironment was constructed to reduce the water dissociation activity and effectively inhibit the hydrogen evolution reaction (HER). HP-ZnO-500 @ 2-NTL was obtained by modifying hierarchical porous zinc oxide (HP-ZnO-500) with the hydrophobic 2-naphthalenethiol (2-NTL). The hydrophobic surface of HP-ZnO-500 @ 2-NTL was easily enriched with CO2 gas under the influence of the “plastron effect”, and the surface hydrophobic film stabilized the M–H bond. Thus, HER was suppressed. At − 1.0 V vs. RHE, HP-ZnO-500 @ 2-NTL achieved a faradaic efficiency of CO (FECO) as high as 83.0%, and displayed high catalytic activity in a wide potential range. The “MC-PMO” strategy and “HG-MO” strategy reported herein are universal and are expected to guide the further preparation and modification of different metal-based porous metal oxides for sustainable CO2RR." @default.
• W4303453721 created "2022-10-07" @default.
• W4303453721 creator A5011087220 @default.
• W4303453721 creator A5017724179 @default.
• W4303453721 creator A5023293298 @default.
• W4303453721 creator A5025274226 @default.
• W4303453721 creator A5046245039 @default.
• W4303453721 creator A5050836770 @default.
• W4303453721 creator A5076758514 @default.
• W4303453721 creator A5076853026 @default.
• W4303453721 date "2022-11-01" @default.
• W4303453721 modified "2023-09-27" @default.
• W4303453721 title "Preparation of hydrophobic three-dimensional hierarchical porous zinc oxide for the promotion of electrochemical CO2 reduction" @default.
• W4303453721 cites W1915333672 @default.
• W4303453721 cites W1965362556 @default.
• W4303453721 cites W1969918942 @default.
• W4303453721 cites W1976877249 @default.
• W4303453721 cites W1987664387 @default.
• W4303453721 cites W1992591486 @default.
• W4303453721 cites W2014808121 @default.
• W4303453721 cites W2019257484 @default.
• W4303453721 cites W2022462224 @default.
• W4303453721 cites W2027310902 @default.
• W4303453721 cites W2033380066 @default.
• W4303453721 cites W2034225029 @default.
• W4303453721 cites W2060441729 @default.
• W4303453721 cites W2068657979 @default.
• W4303453721 cites W2078340316 @default.
• W4303453721 cites W2313553769 @default.
• W4303453721 cites W2315932535 @default.
• W4303453721 cites W2320849513 @default.
• W4303453721 cites W2323135648 @default.
• W4303453721 cites W2418297389 @default.
• W4303453721 cites W2493300873 @default.
• W4303453721 cites W2518178591 @default.
• W4303453721 cites W2573313258 @default.
• W4303453721 cites W2766470925 @default.
• W4303453721 cites W2784681531 @default.
• W4303453721 cites W2796702385 @default.
• W4303453721 cites W2805796463 @default.
• W4303453721 cites W2883336409 @default.
• W4303453721 cites W2888265146 @default.
• W4303453721 cites W2888420286 @default.
• W4303453721 cites W2890912281 @default.
• W4303453721 cites W2901284853 @default.
• W4303453721 cites W2908246121 @default.
• W4303453721 cites W2912313041 @default.
• W4303453721 cites W2930586923 @default.
• W4303453721 cites W2954959763 @default.
• W4303453721 cites W2965193464 @default.
• W4303453721 cites W2969730208 @default.
• W4303453721 cites W2972739927 @default.
• W4303453721 cites W2995340737 @default.
• W4303453721 cites W3006444707 @default.
• W4303453721 cites W3012118139 @default.
• W4303453721 cites W3022715573 @default.
• W4303453721 cites W3024404621 @default.
• W4303453721 cites W3030730120 @default.
• W4303453721 cites W3034714081 @default.
• W4303453721 cites W3038488396 @default.
• W4303453721 cites W3041085575 @default.
• W4303453721 cites W3082676360 @default.
• W4303453721 cites W3086801199 @default.
• W4303453721 cites W3095473153 @default.
• W4303453721 cites W3106950296 @default.
• W4303453721 cites W3121654864 @default.
• W4303453721 cites W3127820278 @default.
• W4303453721 cites W3136829626 @default.
• W4303453721 cites W3142018483 @default.
• W4303453721 cites W3145929633 @default.
• W4303453721 cites W3153367922 @default.
• W4303453721 cites W3155378264 @default.
• W4303453721 cites W3160596081 @default.
• W4303453721 cites W3161200783 @default.
• W4303453721 cites W3195232730 @default.
• W4303453721 cites W3210460422 @default.
• W4303453721 cites W4200437361 @default.
• W4303453721 cites W4206509748 @default.
• W4303453721 cites W4211095005 @default.
• W4303453721 cites W4220884467 @default.
• W4303453721 cites W4223455719 @default.
• W4303453721 cites W4225512312 @default.
• W4303453721 cites W4244040320 @default.
• W4303453721 doi "https://doi.org/10.1016/j.jcou.2022.102256" @default.
• W4303453721 hasPublicationYear "2022" @default.
• W4303453721 type Work @default.
• W4303453721 citedByCount "0" @default.
• W4303453721 crossrefType "journal-article" @default.
• W4303453721 hasAuthorship W4303453721A5011087220 @default.
• W4303453721 hasAuthorship W4303453721A5017724179 @default.
• W4303453721 hasAuthorship W4303453721A5023293298 @default.
• W4303453721 hasAuthorship W4303453721A5025274226 @default.
• W4303453721 hasAuthorship W4303453721A5046245039 @default.
• W4303453721 hasAuthorship W4303453721A5050836770 @default.
• W4303453721 hasAuthorship W4303453721A5076758514 @default.
• W4303453721 hasAuthorship W4303453721A5076853026 @default.
• W4303453721 hasConcept C127413603 @default.
• W4303453721 hasConcept C130349721 @default.

• next