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- W4303629098 endingPage "141319" @default.
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- W4303629098 abstract "Defect and hollow structure on transition metal sulfides can produce abundant active sites and shorten electron/ion diffusion paths, improving the conductivity of electrochemically active materials. In this study, an effective strategy was proposed for preparing r-NiCo2S4 electrode materials with sulfur vacancies and hollow structures and resulted excellent electrochemical performance through ligand exchange followed chemical reduction. Due to the unique structure, the prepared r-NiCo2S4 electrode exhibited excellent specific capacitance (1406.4 F g−1 at 1 A g−1) and rate capacity (90.03%). Additionally, a hybrid supercapacitor r-NiCo2S4//AC HSC was assembled using r-NiCo2S4 as the positive electrode and AC as the negative electrode. It presented an excellent energy density of 43.8 Wh kg−1 under 800 W kg−1 and cycling performance with 93.93% capacity retention after 10,000 cycles at 5 A g−1. This study provided a simple strategy for design and optimization of electrode materials with a unique hollow structure and sulfur vacancies." @default.
- W4303629098 created "2022-10-08" @default.
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- W4303629098 date "2022-12-01" @default.
- W4303629098 modified "2023-10-16" @default.
- W4303629098 title "Metal-organic frameworks (MOFs) derived hollow microspheres with rich sulfur vacancies for hybrid supercapacitors" @default.
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- W4303629098 doi "https://doi.org/10.1016/j.electacta.2022.141319" @default.
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