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• W4303953733 abstract "A diglyme solution of Na[cyclo-P5 ] (1) reacts with alkynes and isolobal nitriles and phosphaalkynes to afford the otherwise elusive (aza)phospholide anions 2 a-c, 4 a,b, and 6. The reaction of Na[cyclo-P5 ] with alkynes and nitriles was studied by means of DFT methods, which suggested a concerted mechanism for the formation of 2 a and 4 b. The anions 2 a-c, 4 a,b, and 6 coordinate in an η5 -fashion towards FeII to give the sandwich (aza)phosphametallocenes 3 a-c, 5 a,b and 7 in moderate to good yields. The new compounds were characterized by means of multinuclear NMR spectroscopy, single-crystal X-ray diffraction and cyclic voltammetry." @default.
• W4303953733 created "2022-10-10" @default.
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• W4303953733 date "2022-11-15" @default.
• W4303953733 modified "2023-10-05" @default.
• W4303953733 title "Reactivity of Sodium Pentaphospholide Na[<i>cyclo</i>‐P₅] towards C≡E (E=C, N, P) Triple Bonds" @default.
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• W4303953733 doi "https://doi.org/10.1002/chem.202203056" @default.
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