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• W4303959024 startingPage "6597" @default.
• W4303959024 abstract "The term matere bond has been recently used to refer to an attractive noncovalent interaction between any element of group 7 acting as an electrophile and any atom (or group of atoms) acting as a nucleophile. The utilization of metals such as σ-hole donors is starting to attract the attention of the scientific community. In this manuscript, a comparison between matere bonds and well-known σ-hole interactions (halogen and chalcogen bonds) is carried out using three X-ray structures, retrieved from the Cambridge structural database (CSD), and density functional theory calculations (DFT). The novelty of this work resides in the utilization of a neutral Re(VII) system as the matere bond donor and multivalent chalcogen and halogen donors. In fact, as far as our knowledge extends, the description of σ-hole interactions in Se(VI) is unprecedented in the literature. The σ-hole interactions in Re(VII), Se(VI) and Cl(VII) electron acceptors are analyzed and compared using several computational tools." @default.
• W4303959024 created "2022-10-10" @default.
• W4303959024 creator A5007717229 @default.
• W4303959024 creator A5037112571 @default.
• W4303959024 date "2022-10-05" @default.
• W4303959024 modified "2023-10-14" @default.
• W4303959024 title "Matere Bonds vs. Multivalent Halogen and Chalcogen Bonds: Three Case Studies" @default.
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• W4303959024 doi "https://doi.org/10.3390/molecules27196597" @default.
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