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• W4303959097 abstract "We herein describe a general approach to 5-trifluoromethyl 1,2,4-triazoles via the [3 + 2]-cycloaddition of nitrile imines generated in situ from hydrazonyl chloride with CF3CN, utilizing 2,2,2-trifluoroacetaldehyde O-(aryl)oxime as the precursor of trifluoroacetonitrile. Various functional groups, including alkyl-substituted hydrazonyl chloride, were tolerated during cycloaddition. Furthermore, the gram-scale synthesis and common downstream transformations proved the potential synthetic relevance of this developed methodology." @default.
• W4303959097 created "2022-10-10" @default.
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• W4303959097 date "2022-10-04" @default.
• W4303959097 modified "2023-09-26" @default.
• W4303959097 title "Regioselective Synthesis of 5-Trifluoromethyl 1,2,4-Triazoles via [3 + 2]-Cycloaddition of Nitrile Imines with CF3CN" @default.
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• W4303959097 doi "https://doi.org/10.3390/molecules27196568" @default.
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