FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4304080223> ?p ?o ?g. }

• W4304080223 endingPage "139713" @default.
• W4304080223 startingPage "139713" @default.
• W4304080223 abstract "• For the first time, specific binding sites for C 2 H 2 are constructed utilizing the MOFs interpenetration nets. • The synergy of hydrogen bond anchoring and strong Tb···C≡C electrostatic interaction enhances the C 2 H 2 capture. • High C 2 H 2 capacity and excellent selectivity over CO 2 and C 2 H 4 . • Detailed theoretical calculations explore the mechanism of host-guest combination. Efficient separation of C 2 H 2 /CO 2 and C 2 H 2 /C 2 H 4 is necessary and challenging for industrial processes. The traditional method of pore sieving has great limitations for separating gases with similar characteristics. Herein, we report a new case ( UPC-80 ) with the help of C 2 H 2 anchoring traps constructed by 4-fold interpenetration nets for gas separation. The single-component adsorption isotherms indicate that UPC-80 adsorbs more C 2 H 2 than C 2 H 4 and CO 2 , resulting in high adsorption selectivities of 6.34 and 4.78 for C 2 H 2 /CO 2 and C 2 H 2 /C 2 H 4 at 298 K, respectively. Laboratory-scale fixed-bed breakthrough experiments verify the efficient separation ability of UPC-80 toward the C 2 H 2 /CO 2 and C 2 H 2 /C 2 H 4 gas mixtures, remaining separation stability with negligible capacity loss. Theoretical simulations confirm that the good separation performance can be attributed to the anchoring of C 2 H 2 by two Tb 2 (COO) 6 clusters in adjacent interpenetration nets, as well as the strong electrostatic interaction. UPC-80 makes the first exploration to obtain specific C 2 H 2 binding sites by interpenetrated networks, becoming an excellent candidate as porous adsorbent for separating C 2 H 2 /CO 2 and C 2 H 2 /C 2 H 4 ." @default.
• W4304080223 created "2022-10-10" @default.
• W4304080223 creator A5010398730 @default.
• W4304080223 creator A5024136853 @default.
• W4304080223 creator A5026604076 @default.
• W4304080223 creator A5031617363 @default.
• W4304080223 creator A5051301975 @default.
• W4304080223 creator A5056830441 @default.
• W4304080223 creator A5061805059 @default.
• W4304080223 creator A5063818470 @default.
• W4304080223 creator A5070674026 @default.
• W4304080223 creator A5086495232 @default.
• W4304080223 creator A5089901400 @default.
• W4304080223 date "2023-02-01" @default.
• W4304080223 modified "2023-10-05" @default.
• W4304080223 title "Constructing C2H2 anchoring traps within MOF interpenetration nets as C2H2/CO2 and C2H2/C2H4 bifunctional separator" @default.
• W4304080223 cites W2048287782 @default.
• W4304080223 cites W2062904068 @default.
• W4304080223 cites W2091161882 @default.
• W4304080223 cites W2102830904 @default.
• W4304080223 cites W2109311979 @default.
• W4304080223 cites W2263926059 @default.
• W4304080223 cites W2329775500 @default.
• W4304080223 cites W2367219829 @default.
• W4304080223 cites W2402426102 @default.
• W4304080223 cites W2517475376 @default.
• W4304080223 cites W2621160901 @default.
• W4304080223 cites W2742242099 @default.
• W4304080223 cites W2907892525 @default.
• W4304080223 cites W2911787752 @default.
• W4304080223 cites W2911840138 @default.
• W4304080223 cites W2915735482 @default.
• W4304080223 cites W2919155534 @default.
• W4304080223 cites W2923732278 @default.
• W4304080223 cites W2935825491 @default.
• W4304080223 cites W2957162083 @default.
• W4304080223 cites W2963816825 @default.
• W4304080223 cites W2971278545 @default.
• W4304080223 cites W3000621344 @default.
• W4304080223 cites W3007016672 @default.
• W4304080223 cites W3007044642 @default.
• W4304080223 cites W3014996390 @default.
• W4304080223 cites W3022181461 @default.
• W4304080223 cites W3044404080 @default.
• W4304080223 cites W3081154292 @default.
• W4304080223 cites W3094186035 @default.
• W4304080223 cites W3109014524 @default.
• W4304080223 cites W3128645345 @default.
• W4304080223 cites W3133123102 @default.
• W4304080223 cites W3157135685 @default.
• W4304080223 cites W3198059400 @default.
• W4304080223 cites W3209187718 @default.
• W4304080223 cites W3210009884 @default.
• W4304080223 cites W3210955874 @default.
• W4304080223 cites W3214353571 @default.
• W4304080223 cites W3215645701 @default.
• W4304080223 cites W3216552656 @default.
• W4304080223 cites W4200098694 @default.
• W4304080223 cites W4200219264 @default.
• W4304080223 cites W4226181981 @default.
• W4304080223 doi "https://doi.org/10.1016/j.cej.2022.139713" @default.
• W4304080223 hasPublicationYear "2023" @default.
• W4304080223 type Work @default.
• W4304080223 citedByCount "14" @default.
• W4304080223 countsByYear W43040802232023 @default.
• W4304080223 crossrefType "journal-article" @default.
• W4304080223 hasAuthorship W4304080223A5010398730 @default.
• W4304080223 hasAuthorship W4304080223A5024136853 @default.
• W4304080223 hasAuthorship W4304080223A5026604076 @default.
• W4304080223 hasAuthorship W4304080223A5031617363 @default.
• W4304080223 hasAuthorship W4304080223A5051301975 @default.
• W4304080223 hasAuthorship W4304080223A5056830441 @default.
• W4304080223 hasAuthorship W4304080223A5061805059 @default.
• W4304080223 hasAuthorship W4304080223A5063818470 @default.
• W4304080223 hasAuthorship W4304080223A5070674026 @default.
• W4304080223 hasAuthorship W4304080223A5086495232 @default.
• W4304080223 hasAuthorship W4304080223A5089901400 @default.
• W4304080223 hasConcept C121332964 @default.
• W4304080223 hasConcept C127413603 @default.
• W4304080223 hasConcept C161790260 @default.
• W4304080223 hasConcept C178790620 @default.
• W4304080223 hasConcept C18483071 @default.
• W4304080223 hasConcept C185004128 @default.
• W4304080223 hasConcept C185592680 @default.
• W4304080223 hasConcept C192562407 @default.
• W4304080223 hasConcept C2780443040 @default.
• W4304080223 hasConcept C66938386 @default.
• W4304080223 hasConcept C97355855 @default.
• W4304080223 hasConceptScore W4304080223C121332964 @default.
• W4304080223 hasConceptScore W4304080223C127413603 @default.
• W4304080223 hasConceptScore W4304080223C161790260 @default.
• W4304080223 hasConceptScore W4304080223C178790620 @default.
• W4304080223 hasConceptScore W4304080223C18483071 @default.
• W4304080223 hasConceptScore W4304080223C185004128 @default.
• W4304080223 hasConceptScore W4304080223C185592680 @default.
• W4304080223 hasConceptScore W4304080223C192562407 @default.
• W4304080223 hasConceptScore W4304080223C2780443040 @default.
• W4304080223 hasConceptScore W4304080223C66938386 @default.

• next