Matches in SemOpenAlex for { <https://semopenalex.org/work/W4304123911> ?p ?o ?g. }
- W4304123911 endingPage "2208438" @default.
- W4304123911 startingPage "2208438" @default.
- W4304123911 abstract "The interaction mechanism between the reacting species and the active site of α-Fe2 O3 -based photoanodes in photoelectrochemical methanol conversion reaction is still ambiguous. Herein, a simple two-step strategy is demonstrated to fabricate a porous α-Fe2 O3 /CoFe2 O4 heterojunction for the methanol conversion reaction. The influence of the electronic structure of active site and interfacial effect on the reaction are investigated by constructing two different FeO6 octahedral configurations and heterogeneous structures. The optimal sample ZnFeCo-2 affords high photocurrent density of 1.17 mA cm-2 at 0.5 V vs Ag/AgCl, which is 3.2 times than that of ZnFe (0.37 mA cm-2 ). Meanwhile, the ZnFeCo-2 also exhibits 97.8% Faraday efficiency of CH3 OH to HCHO, and long-term stability over 40 h. Furthermore, density functional theory calculations reveal that the heterostructured α-Fe2 O3 /CoFe2 O4 with favorable electron transfer effectively lowers methanol adsorption, C-H bond activation, and HCHO desorption energy relative to the pristine α-Fe2 O3 , resulting in excellent methanol conversion efficiency." @default.
- W4304123911 created "2022-10-11" @default.
- W4304123911 creator A5012834298 @default.
- W4304123911 creator A5013972114 @default.
- W4304123911 creator A5023109825 @default.
- W4304123911 creator A5043307587 @default.
- W4304123911 creator A5082620505 @default.
- W4304123911 creator A5088889008 @default.
- W4304123911 date "2022-11-07" @default.
- W4304123911 modified "2023-10-18" @default.
- W4304123911 title "Activating C–H Bonds by Tuning Fe Sites and an Interfacial Effect for Enhanced Methanol Oxidation" @default.
- W4304123911 cites W1978326533 @default.
- W4304123911 cites W2015856769 @default.
- W4304123911 cites W2060034805 @default.
- W4304123911 cites W2129515724 @default.
- W4304123911 cites W2194932601 @default.
- W4304123911 cites W2296420697 @default.
- W4304123911 cites W2485875428 @default.
- W4304123911 cites W2507759105 @default.
- W4304123911 cites W2616613391 @default.
- W4304123911 cites W2765773466 @default.
- W4304123911 cites W2802053820 @default.
- W4304123911 cites W2889532685 @default.
- W4304123911 cites W2908404354 @default.
- W4304123911 cites W2914352209 @default.
- W4304123911 cites W2935217939 @default.
- W4304123911 cites W2942586823 @default.
- W4304123911 cites W2944437544 @default.
- W4304123911 cites W2946232728 @default.
- W4304123911 cites W2947535410 @default.
- W4304123911 cites W2962944603 @default.
- W4304123911 cites W2981813893 @default.
- W4304123911 cites W2992542521 @default.
- W4304123911 cites W3014796521 @default.
- W4304123911 cites W3023666927 @default.
- W4304123911 cites W3030011157 @default.
- W4304123911 cites W3033392125 @default.
- W4304123911 cites W3037157774 @default.
- W4304123911 cites W3047588620 @default.
- W4304123911 cites W3048911892 @default.
- W4304123911 cites W3087490316 @default.
- W4304123911 cites W3091875934 @default.
- W4304123911 cites W3093625094 @default.
- W4304123911 cites W3122805476 @default.
- W4304123911 cites W3126738779 @default.
- W4304123911 cites W3127628390 @default.
- W4304123911 cites W3130356750 @default.
- W4304123911 cites W3132281144 @default.
- W4304123911 cites W3132406900 @default.
- W4304123911 cites W3134291833 @default.
- W4304123911 cites W3158583020 @default.
- W4304123911 cites W3169054595 @default.
- W4304123911 cites W3176867399 @default.
- W4304123911 cites W3185469521 @default.
- W4304123911 cites W3187258680 @default.
- W4304123911 cites W3188008366 @default.
- W4304123911 cites W3199417592 @default.
- W4304123911 cites W3205954301 @default.
- W4304123911 cites W3211728128 @default.
- W4304123911 cites W3216856263 @default.
- W4304123911 cites W4205968367 @default.
- W4304123911 doi "https://doi.org/10.1002/adma.202208438" @default.
- W4304123911 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/36216372" @default.
- W4304123911 hasPublicationYear "2022" @default.
- W4304123911 type Work @default.
- W4304123911 citedByCount "21" @default.
- W4304123911 countsByYear W43041239112022 @default.
- W4304123911 countsByYear W43041239112023 @default.
- W4304123911 crossrefType "journal-article" @default.
- W4304123911 hasAuthorship W4304123911A5012834298 @default.
- W4304123911 hasAuthorship W4304123911A5013972114 @default.
- W4304123911 hasAuthorship W4304123911A5023109825 @default.
- W4304123911 hasAuthorship W4304123911A5043307587 @default.
- W4304123911 hasAuthorship W4304123911A5082620505 @default.
- W4304123911 hasAuthorship W4304123911A5088889008 @default.
- W4304123911 hasConcept C115624301 @default.
- W4304123911 hasConcept C123669783 @default.
- W4304123911 hasConcept C127413603 @default.
- W4304123911 hasConcept C147597530 @default.
- W4304123911 hasConcept C147789679 @default.
- W4304123911 hasConcept C150394285 @default.
- W4304123911 hasConcept C152365726 @default.
- W4304123911 hasConcept C161790260 @default.
- W4304123911 hasConcept C162711632 @default.
- W4304123911 hasConcept C178790620 @default.
- W4304123911 hasConcept C185592680 @default.
- W4304123911 hasConcept C192562407 @default.
- W4304123911 hasConcept C198819137 @default.
- W4304123911 hasConcept C206991015 @default.
- W4304123911 hasConcept C2779607525 @default.
- W4304123911 hasConcept C2779845233 @default.
- W4304123911 hasConcept C42360764 @default.
- W4304123911 hasConcept C49040817 @default.
- W4304123911 hasConcept C55493867 @default.
- W4304123911 hasConcept C75473681 @default.
- W4304123911 hasConcept C79794668 @default.
- W4304123911 hasConcept C8010536 @default.
- W4304123911 hasConcept C86025842 @default.