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- W4304193500 abstract "Perfluoroalkylation is important for late-stage modification of biologically active molecules. Herein, we report a protocol for visible-light-induced perfluoroalkylation reactions of aryl acrylic acids. These reactions, which use perfluoroalkyl iodides as radical precursors and inexpensive eosin Y as a photocatalyst, proceed in a decarboxylative manner. The easy accessibility of perfluoroalkyl iodides and the broad substrate scope, mild conditions, and metal-free catalyst make this protocol applicable for the transformation of inexpensive raw materials to high-value chemicals." @default.
- W4304193500 created "2022-10-11" @default.
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- W4304193500 date "2022-10-11" @default.
- W4304193500 modified "2023-10-16" @default.
- W4304193500 title "Visible-Light-Induced Metal-Free Decarboxylative Perfluoroalkylation of Aryl Acrylic Acids" @default.
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- W4304193500 doi "https://doi.org/10.1021/acs.orglett.2c03088" @default.
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