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- W4304687593 abstract "A new method to access β-keto-gem-diborylalkanes, by direct deoxygenative radical addition of aromatic carboxylic acids to gem-dibortlalkenes, is described. The reaction proceeds under mild photoredox catalysis and involves the photochemical C-O bond activation of aromatic carboxylic acids in the presence of PPh3 . It generates an acyl radical, which further undergoes an additional reaction with gem-diborylalkenes to form an α-gem-diboryl alkyl radical intermediate, which then reduces to the corresponding anion, which after protonation, affords the β-keto-gem-diborylalkane product. Moreover, the same scenario has been extended to the vinyl boronic esters, for example, gem-(Ar, Bpin)-alkenes, and gem-(Alkyl, Bpin)-alkenes. Importantly, this protocol provides a general platform for the late-stage functionalization of bio-active and drug molecules containing a carboxylic acid group." @default.
- W4304687593 created "2022-10-12" @default.
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- W4304687593 date "2022-11-24" @default.
- W4304687593 modified "2023-09-30" @default.
- W4304687593 title "Photoredox‐Mediated Deoxygenative Radical Additions of Aromatic Acids to Vinyl Boronic Esters and <i>gem</i>‐Diborylalkenes**" @default.
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- W4304687593 doi "https://doi.org/10.1002/chem.202202646" @default.
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