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- W4304756290 abstract "Biobased materials have served as an attractive alternative to replace current petroleum-based plastics because of their abundant biorenewable feedstocks and potential degradability. Here we prepared a class of seven-membered ring carbonates containing biobased Diels–Alder adduct moieties. The bifunctional monomers M1 and M2 exhibited excellent reactivity for both ring-opening polymerization and ring-opening metathesis polymerization, yielding functionalizable aliphatic polycarbonates and poly(cyclic olefin)s with a range of Tg values from 84 to 194 °C. The resulting polymers can be postpolymerization functionalized by “click”, cross-linking, hydrogenation, hydrolysis, and retro-Diels–Alder reactions, which appeared to be powerful tools to tune the thermal and mechanical properties of the resulting polymers. Ultimately, the resulting polycarbonate P(M1)ROP-SC6H13 possessed polyolefin-like mechanical performance. These polycarbonates can be completely hydrolyzed into their corresponding starting material diols, demonstrating a potential close-loop life cycle of P(M)ROP. Remarkably, this novel monomer design strategy enabled diverse functionalities to be incorporated, providing access to biobased materials with tunable properties." @default.
- W4304756290 created "2022-10-13" @default.
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- W4304756290 date "2022-10-12" @default.
- W4304756290 modified "2023-10-18" @default.
- W4304756290 title "Biobased Bifunctional Monomers toward Functionalizable Polycarbonates and Poly(cyclic olefin)s with Tunable Properties" @default.
- W4304756290 cites W1915962847 @default.
- W4304756290 cites W1943835583 @default.
- W4304756290 cites W1969443543 @default.
- W4304756290 cites W1969768494 @default.
- W4304756290 cites W1971695057 @default.
- W4304756290 cites W1976147365 @default.
- W4304756290 cites W1980957090 @default.
- W4304756290 cites W1981512732 @default.
- W4304756290 cites W1999650994 @default.
- W4304756290 cites W2007177369 @default.
- W4304756290 cites W2016954735 @default.
- W4304756290 cites W2054310958 @default.
- W4304756290 cites W2060406819 @default.
- W4304756290 cites W2063430112 @default.
- W4304756290 cites W2071726528 @default.
- W4304756290 cites W2085881347 @default.
- W4304756290 cites W2114863424 @default.
- W4304756290 cites W2125462378 @default.
- W4304756290 cites W2130472233 @default.
- W4304756290 cites W2139235318 @default.
- W4304756290 cites W2139992033 @default.
- W4304756290 cites W2154052567 @default.
- W4304756290 cites W2154678311 @default.
- W4304756290 cites W2157031476 @default.
- W4304756290 cites W2161652710 @default.
- W4304756290 cites W2179230145 @default.
- W4304756290 cites W2321571472 @default.
- W4304756290 cites W2327933281 @default.
- W4304756290 cites W2437377606 @default.
- W4304756290 cites W2462206851 @default.
- W4304756290 cites W2483057761 @default.
- W4304756290 cites W2515610915 @default.
- W4304756290 cites W2518254623 @default.
- W4304756290 cites W2522678158 @default.
- W4304756290 cites W2555054449 @default.
- W4304756290 cites W2563186293 @default.
- W4304756290 cites W2578979395 @default.
- W4304756290 cites W2587176034 @default.
- W4304756290 cites W2587877550 @default.
- W4304756290 cites W2596417516 @default.
- W4304756290 cites W2602241032 @default.
- W4304756290 cites W2607863303 @default.
- W4304756290 cites W2610781942 @default.
- W4304756290 cites W2660478160 @default.
- W4304756290 cites W2684871860 @default.
- W4304756290 cites W2733732064 @default.
- W4304756290 cites W2754385884 @default.
- W4304756290 cites W2765210351 @default.
- W4304756290 cites W2765471533 @default.
- W4304756290 cites W2769219263 @default.
- W4304756290 cites W2789006222 @default.
- W4304756290 cites W2795586786 @default.
- W4304756290 cites W2796534223 @default.
- W4304756290 cites W2799873627 @default.
- W4304756290 cites W2884514405 @default.
- W4304756290 cites W2884892365 @default.
- W4304756290 cites W2887500702 @default.
- W4304756290 cites W2901774347 @default.
- W4304756290 cites W2904915452 @default.
- W4304756290 cites W2956225228 @default.
- W4304756290 cites W2964713109 @default.
- W4304756290 cites W2969315379 @default.
- W4304756290 cites W2994881927 @default.
- W4304756290 cites W2996534121 @default.
- W4304756290 cites W3036224634 @default.
- W4304756290 cites W3045554671 @default.
- W4304756290 cites W3087313014 @default.
- W4304756290 cites W3088132266 @default.
- W4304756290 cites W3112078479 @default.
- W4304756290 cites W3113658376 @default.
- W4304756290 cites W3130093081 @default.
- W4304756290 cites W3169398296 @default.
- W4304756290 cites W3173151188 @default.
- W4304756290 cites W3191870946 @default.
- W4304756290 cites W3200544906 @default.
- W4304756290 cites W3202133093 @default.
- W4304756290 cites W3204751640 @default.
- W4304756290 cites W4200460255 @default.
- W4304756290 cites W4205582861 @default.
- W4304756290 cites W4210866693 @default.
- W4304756290 cites W4224245693 @default.
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- W4304756290 doi "https://doi.org/10.1021/acs.macromol.2c01754" @default.
- W4304756290 hasPublicationYear "2022" @default.
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