Matches in SemOpenAlex for { <https://semopenalex.org/work/W4304889493> ?p ?o ?g. }
- W4304889493 abstract "Abstract A ligand‐controlled rhodium‐catalyzed regiodivergent arylation of alkenylthianthrenium salts with arylboroxines which allows the synthesis of terminal and internal alkene products in a switchable manner is reported. The use of a diene ligand guides the reaction toward cine‐arylation affording terminal alkenes, while the use of a phosphine ligand switches the reaction to ipso‐arylation exclusively giving internal alkenes. Deuterium labelling studies and DFT computations were carried out to investigate the mechanism." @default.
- W4304889493 created "2022-10-13" @default.
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- W4304889493 date "2022-11-09" @default.
- W4304889493 modified "2023-10-12" @default.
- W4304889493 title "Rhodium‐Catalyzed Divergent Arylation of Alkenylsulfonium Salts with Arylboroxines" @default.
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- W4304889493 doi "https://doi.org/10.1002/anie.202212522" @default.
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