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- W4304893242 abstract "In this work, the molecular aluminium dihydride complex bearing an N, N’-chelated conjugated bis-guanidinate (CBG) ligand is used as a catalyst for reducing a wide range of aryl and alkyl esters with good tolerance of alkene (C=C), alkyne (C≡C), halides (Cl, Br, I and F), nitrile (C≡N), and nitro (NO2) functionalities. Further, we investigated the catalytic application of aluminium dihydride in the C−O bond cleavage of alkyl and aryl epoxides into corresponding branched Markovnikov ring-opening products. In addition, the chemoselective intermolecular reduction of esters over other reducible functional groups, such as amides and alkenes, has been established. Intermediates are isolated and characterized by NMR and HRMS studies, which confirm the probable catalytic cycles for the hydroboration of esters and epoxides." @default.
- W4304893242 created "2022-10-13" @default.
- W4304893242 creator A5019067952 @default.
- W4304893242 creator A5020186722 @default.
- W4304893242 creator A5040168222 @default.
- W4304893242 date "2022-11-30" @default.
- W4304893242 modified "2023-09-27" @default.
- W4304893242 title "Aluminium‐Catalyzed Selective Hydroboration of Esters and Epoxides to Alcohols: C−O Bond Activation" @default.
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