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- W4304959913 abstract "We report here the development of a rotating molecular switch based on metal-catalyzed reversible (de)-hydrogenation. Under an argon atmosphere, acceptorless dehydrogenation induces a switch from an alcohol to a ketone, while reversing to a hydrogen pressure switches back the system to the alcohol. Based on a tolane scaffold, such reversible (de)-hydrogenation enables 180° rotation. The absence of waste accumulation in a switch relying on chemical stimuli is of great significance and could potentially be applied to the design of efficient complex molecular machines." @default.
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- W4304959913 date "2022-11-15" @default.
- W4304959913 modified "2023-10-16" @default.
- W4304959913 title "Catalytic Reversible (De)hydrogenation To Rotate a Chemically Fueled Molecular Switch" @default.
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- W4304959913 doi "https://doi.org/10.1002/anie.202214763" @default.
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