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• W4305072198 abstract "Deuterated compounds have important applications, especially in the pharmaceutical field. Hence, the development of new and straightforward synthetic methods for the construction of deuterated compounds is becoming more and more attractive. We describe here a copper-catalyzed hydroxymethylation of aryl olefins with CO and D2 as the source of hydroxymethyl group. Various multideuterium 1,1,2,3-d4-labeled alcohols were produced directly. Mechanistic investigations established that the hydroxymethylation reaction proceeds via an in situ-generated carbon carbene intermediate." @default.
• W4305072198 created "2022-10-14" @default.
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• W4305072198 date "2022-10-13" @default.
• W4305072198 modified "2023-09-24" @default.
• W4305072198 title "Copper-Catalyzed Synthesis of Multideuterium-Labeled Alcohols from Styrenes with CO and D₂ as the Source of the Hydroxymethyl Group" @default.
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• W4305072198 doi "https://doi.org/10.1021/acs.orglett.2c03189" @default.
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