Matches in SemOpenAlex for { <https://semopenalex.org/work/W4305072324> ?p ?o ?g. }
- W4305072324 endingPage "179370" @default.
- W4305072324 startingPage "179370" @default.
- W4305072324 abstract "A robust procedure for isothermal kinetic evaluation of Differential Scanning Calorimetry (DSC) measurements of polymers using the Kolmogorov-Johnson-Mehl-Avrami (KJMA) equation is proposed. This procedure takes into account the experimental uncertainties for short (initial deflection) and long (secondary crystallization) measurement times. This procedure is applied to the isothermal crystallization of various commercially available isotactic polypropylenes (iPP) in the temperature range between 10°C and 120°C. Further measurements are performed on unfilled iPP and iPP highly filled with calcium carbonate. The measurements were performed using Fast Differential Scanning Calorimetry (FDSC). Evaluation of the crystallization kinetics indicates homogeneous nucleation in the temperature range of mesophase formation below 60°C. With decreasing temperature, the crystallization is more affected by diffusion control and/or termination of growth at an early crystallization stage During α-phase formation (above 60°C), crystallization is heterogeneously nucleated. Depending on the sample, growth occurs at a constant rate or is diffusion controlled. Polypropylene highly filled with calcium carbonate shows an additional α-phase crystallization process. The KJMA evaluation indicates that this process is homogeneously nucleated." @default.
- W4305072324 created "2022-10-14" @default.
- W4305072324 creator A5002875520 @default.
- W4305072324 date "2022-12-01" @default.
- W4305072324 modified "2023-10-17" @default.
- W4305072324 title "Comments on isothermal crystallization kinetics of polymers: Polypropylene at high supercooling" @default.
- W4305072324 cites W1489873057 @default.
- W4305072324 cites W1508746886 @default.
- W4305072324 cites W1963917436 @default.
- W4305072324 cites W1966492280 @default.
- W4305072324 cites W1966889158 @default.
- W4305072324 cites W1969886796 @default.
- W4305072324 cites W1972142634 @default.
- W4305072324 cites W1972643371 @default.
- W4305072324 cites W1973328884 @default.
- W4305072324 cites W1974153422 @default.
- W4305072324 cites W1974278981 @default.
- W4305072324 cites W1975983911 @default.
- W4305072324 cites W1976670659 @default.
- W4305072324 cites W1978049668 @default.
- W4305072324 cites W1980197910 @default.
- W4305072324 cites W1982448556 @default.
- W4305072324 cites W1986161258 @default.
- W4305072324 cites W1992797544 @default.
- W4305072324 cites W2003830197 @default.
- W4305072324 cites W2006166600 @default.
- W4305072324 cites W2007765382 @default.
- W4305072324 cites W2009115658 @default.
- W4305072324 cites W2010975431 @default.
- W4305072324 cites W2012691582 @default.
- W4305072324 cites W2017131163 @default.
- W4305072324 cites W2018637356 @default.
- W4305072324 cites W2018723895 @default.
- W4305072324 cites W2020250331 @default.
- W4305072324 cites W2021809492 @default.
- W4305072324 cites W2022898257 @default.
- W4305072324 cites W2024908520 @default.
- W4305072324 cites W2026153278 @default.
- W4305072324 cites W2026784221 @default.
- W4305072324 cites W2033595491 @default.
- W4305072324 cites W2035638476 @default.
- W4305072324 cites W2036152656 @default.
- W4305072324 cites W2039039137 @default.
- W4305072324 cites W2043986052 @default.
- W4305072324 cites W2044695133 @default.
- W4305072324 cites W2045341980 @default.
- W4305072324 cites W2053583001 @default.
- W4305072324 cites W2058605398 @default.
- W4305072324 cites W2059289885 @default.
- W4305072324 cites W2059463008 @default.
- W4305072324 cites W2059899012 @default.
- W4305072324 cites W2062069480 @default.
- W4305072324 cites W2068126409 @default.
- W4305072324 cites W2069143217 @default.
- W4305072324 cites W2070086989 @default.
- W4305072324 cites W2070432272 @default.
- W4305072324 cites W2075358276 @default.
- W4305072324 cites W2076968233 @default.
- W4305072324 cites W2078343410 @default.
- W4305072324 cites W2080565555 @default.
- W4305072324 cites W2083142813 @default.
- W4305072324 cites W2085675929 @default.
- W4305072324 cites W2085751190 @default.
- W4305072324 cites W2086080114 @default.
- W4305072324 cites W2086245916 @default.
- W4305072324 cites W2087294181 @default.
- W4305072324 cites W2087936812 @default.
- W4305072324 cites W2097451654 @default.
- W4305072324 cites W2102140243 @default.
- W4305072324 cites W2131522143 @default.
- W4305072324 cites W2135156383 @default.
- W4305072324 cites W2138355159 @default.
- W4305072324 cites W2165712401 @default.
- W4305072324 cites W2319843557 @default.
- W4305072324 cites W23664121 @default.
- W4305072324 cites W2405448718 @default.
- W4305072324 cites W2415895324 @default.
- W4305072324 cites W2528110869 @default.
- W4305072324 cites W2550018125 @default.
- W4305072324 cites W2735357335 @default.
- W4305072324 cites W2889160878 @default.
- W4305072324 cites W3048253596 @default.
- W4305072324 cites W3215368419 @default.
- W4305072324 cites W4224283990 @default.
- W4305072324 cites W4233312974 @default.
- W4305072324 cites W4245621583 @default.
- W4305072324 doi "https://doi.org/10.1016/j.tca.2022.179370" @default.
- W4305072324 hasPublicationYear "2022" @default.
- W4305072324 type Work @default.
- W4305072324 citedByCount "5" @default.
- W4305072324 countsByYear W43050723242023 @default.
- W4305072324 crossrefType "journal-article" @default.
- W4305072324 hasAuthorship W4305072324A5002875520 @default.
- W4305072324 hasConcept C110530677 @default.
- W4305072324 hasConcept C112964491 @default.
- W4305072324 hasConcept C121332964 @default.
- W4305072324 hasConcept C127413603 @default.
- W4305072324 hasConcept C133347239 @default.