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- W4306293860 endingPage "136896" @default.
- W4306293860 startingPage "136896" @default.
- W4306293860 abstract "A facile hydrothermal route was followed to obtain a ternary composite Ag@AgVO3/rGO/CeVO4 with in-situ deposition of Ag nanoparticles over the AgVO3 nano-belts. The in-situ deposition was promoted and enhanced with the introduction of GO. The as-synthesized composite demonstrated remarkable visible light harvesting efficiency greater than 75% in the visible region. The charge separation and light harvesting properties were achieved through the Z-scheme mechanism mediated through rGO and the electron trapping/Schottky barrier effect from Ag nanoparticles. The reduction in the width of space charge region (∼2.5 times) and simultaneous increase in the density of charge carriers (2.3∗1018) promoted the LED irradiated photocatalytic performance. The decay time of the charge carriers were prolonged in the order of 4.46 s implying the enhancement in the charge separation. The studies were extended to charge trapping and the band structure modelling. The later emphasized on the prominence of Z-scheme mechanism with hole mediated degradation pathway. The LED photocatalysis demonstrated a removal efficiency of 87.20% for MB and 55.51% for phenol with a average AQE of 29.28% (MB) and 13.90% (phenol) for the ternary. The mineralization efficiency determined through TOC analysis was found to be 71.72%, and 66.43% for MB and phenol system respectively." @default.
- W4306293860 created "2022-10-15" @default.
- W4306293860 creator A5021620084 @default.
- W4306293860 creator A5031272492 @default.
- W4306293860 date "2023-01-01" @default.
- W4306293860 modified "2023-10-02" @default.
- W4306293860 title "Z-scheme promoted heterojunction photocatalyst (Ag@AgVO3 /rGO/CeVO4) with improved interfacial charge transfer for efficient removal of aqueous organics irradiated under LED light" @default.
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- W4306293860 doi "https://doi.org/10.1016/j.chemosphere.2022.136896" @default.
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