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- W4306403811 abstract "• The texture properties of hierarchical TS-1 zeolites can be precisely modulated by the TritonX homologues with different amounts of ethoxide. • The mesoporosity and Ti content of hierarchical Ti-rich determine the conversion of benzene. • Introducing additional mesoporosity into the hierarchical TS-1 facilitates the direct the oxidation of benzene. The hydrothermal approach was used to effectively synthesis hierarchical TS-1 utilizing the green and inexpensive surfactant TritonX homologues with varying amounts of ethylene oxide groups. The textural property of obtained materials can be modulated by varying the number of ethylene oxide groups of the TritonX homologues. The mesoporous size of hierarchical TS-1 depends on the micelles size of TritonX homologues. The synthesized samples have significant intracrystalline mesopores with a pore size range of 3.5–4.5 nm. The impact of various ethylene oxide group counts of TritonX homologous on the structure, texture properties, and titanium species was investigated using a variety of characterization methods. The hydroxylation of benzene with the H 2 O 2 as oxidizer was used to investigate the catalytic properties of hierarchical TS-1. The catalytic properties and stability of the resulting materials were noticeably improved in the hydroxylation of benzene in comparison with the traditional TS-1." @default.
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- W4306403811 date "2022-11-01" @default.
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- W4306403811 title "Synthesis of the Hierarchical TS-1 Using TritonX Homologues for Hydroxylation of Benzene" @default.
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- W4306403811 doi "https://doi.org/10.1016/j.mcat.2022.112744" @default.
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